Binuclear copper(II) complexes with acyldihydrazones of 1,4-cyclohexanedicarboxylic acid View Full Text


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Article Info

DATE

2011-05

AUTHORS

V. F. Shul’gin, Yu. V. Trush, O. V. Konnik, E. B. Rusanov, V. Ya. Zub, V. V. Minin

ABSTRACT

The binuclear copper(II) complexes with acyldihydrazones formed by 1,4-cyclohexanedicarboxylic acid and salicylaldehyde or 2-hydroxyacetophenone were synthesized and studied. The structure of the complex with 1,4-cyclohexanedicarboxylic acid bis(salicylidene)hydrazone (H4L1) [Cu2L1(Py)2] was studied by X-ray diffraction. The crystals are triclinic: a = 8.1852(4) Å, b = 8.5157(5) Å, c = 11.6553(7) Å, α = 80.678(3)°, β = 70.041(4)°, γ = 74.803(3)°. Space group , Z = 1. The number of symmetrically independent reflections with I > 2(σ(I)) is 2245, R = 0.0395; Rw = 0.0917. The complex contains two equivalent copper atoms located at a 10.772 Å distance from each other. The coordination polyhedra have a square geometry and are involved in the intermolecular π/π-stacking. The EPR spectra of solutions of the binuclear complexes show an isotropic signal of seven HFS lines (g = 2.113–2.118, ACu ≈ 38 G), indicating interaction between the unpaired electrons and the two equivalent copper nuclei. The possible exchange interaction channels were analyzed. More... »

PAGES

707-712

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0036023611050226

DOI

http://dx.doi.org/10.1134/s0036023611050226

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1041222022


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