Chemical transformation of cluster osmium thioselenochloride Os3S7SeCl8 View Full Text


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Article Info

DATE

2011-04

AUTHORS

S. V. Volkov, Yu. V. Mironov, S. S. Yarovoi, A. I. Smolentsev, O. G. Yanko, L. B. Khar’kova, Z. A. Fokina

ABSTRACT

The binuclear osmium complex Os3S7SeCl8 was prepared by the reaction of cluster chalcogen chloride K6Os2S2O6(CN)8 with an aqueous KCN solution. In the complex, the distance between the osmium atoms is 2.85 Å, and they are linked by μ-SO22− bridges with the OsSOs angle of 75.9°. The osmium coordination number is 6. In the reaction with CN− ligands under study, the individual fragments of the structure are retained; however, the trinuclear cluster skeleton of Os3S7SeCl8 is destroyed. More... »

PAGES

545-548

References to SciGraph publications

  • 1997-09. Synthesis and crystal structure of K4[Re6Se8(CN)6]·3.5H2O in JOURNAL OF STRUCTURAL CHEMISTRY
  • Identifiers

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    http://scigraph.springernature.com/pub.10.1134/s0036023611040279

    DOI

    http://dx.doi.org/10.1134/s0036023611040279

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