Copper(II) trinuclear complex with trimesic acid salicylidene hydrazone: Synthesis, structure, and magnetic properties View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2011-04

AUTHORS

V. F. Shul’gin, O. V. Konnik, R. I. Gurtovoi, A. S. Bogomyakov, V. Ya. Zub, V. V. Minin

ABSTRACT

A trinuclear copper(II) complex of trimesic acid salicylidene hydrazone (H6L) having the composition [Cu3L · 4Py] · CH3OH was synthesized and characterized. By X-ray crystallography, the crystals are triclinic: a = 11.7940(4) Å, b = 13.7241(5) Å, c = 15.8993(6) Å, α = 107.4120(10)°, β = 94.2900(10)°, γ = 105.5650(10)°, space group , Z = 2. The number of symmetrically unique reflections having I > 2σ(I) is 7636, R = 0.0465, and Rw = 0.1198. The newly prepared complex contains, in its unit cell, two [Cu3L · 4Py] molecules which are linked to form a dimer on account of phenoxo bridges (the Cu-O bond length is 2.555 the Cu…Cu distance is 3.348 Separations between them are 9.414, 9.371, and 9.667 of temperature is satisfactorily fitted in terms of a triangular cluster model (−2J = 2.2 cm−1) with extra intermolecular interactions (zJ′ = 0.4 cm−1). EPR spectra of solutions at 360–380 K feature a poorly resolved HFS, whose modeling gives a satisfactory result with allowance for the interaction of unpaired electrons with three equivalent copper nuclei (g = 2.098; aCu = 25.8 × 10−4 cm−1). More... »

PAGES

600-605

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0036023611040243

DOI

http://dx.doi.org/10.1134/s0036023611040243

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1033967059


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