N-(1,5-dimethyl-3-oxo-2-phenyl-1,2-dihydropyrazol-4-yl)-P,P-diphenylamidophosphinate and its complexes with neodymium(III), erbium(III), thorium(IV), and uranyl nitrates: Synthesis and crystal and molecular structure View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2011-04

AUTHORS

E. I. Matrosov, I. B. Goryunova, K. A. Lysenko, M. S. Grigor’ev, A. M. Safiulina, E. I. Goryunov, E. E. Nifant’ev

ABSTRACT

A new phosphoryl-containing ligand based on 4-aminoantipyrine-N-(1,5-dimethyl-3-oxo-2-phenyl-1,2-dihydropyrazol-4-yl)-P,P-diphenylamidophosphinate (L) was synthesized. In crystals, the L molecules were found to be combined in centrosymmetric dimers through N-H…O=C hydrogen bonds. The complexes of L with neodymium(III), erbium(III), thorium(IV), and uranyl nitrates were obtained, and their structures were determined. The bands of the C=O and P=O groups in the IR spectra of these complexes are shifted toward low frequencies (by 50–65 and 40–70 cm−1, respectively), which is indicative of a bidentate coordination of the organophosphorus ligand. According to the X-ray crystallography data, uranyl is bidentately coordinated by both the L molecule (through the C=O and P=O groups) and two nitrate anions. More... »

PAGES

539-544

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s003602361104019x

DOI

http://dx.doi.org/10.1134/s003602361104019x

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1010033312


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