Interaction of K2PdCl4 with aminoalkyldiphosphonic acids View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2011-09

AUTHORS

A. N. Kozachkova, A. V. Dudko, N. V. Tsaryk, V. V. Trachevskii, A. B. Rozhenko, V. I. Pekhn’o

ABSTRACT

Complexing of K2PdCl4 with 3-amino-1-hydroxypropylidene-1,1-diphosphonic acid (AHPDP) and 1-aminoethylidene-1,1-diphosphonic acid (AEDP) was studied by pH titration, spectrophotometry, and 31P NMR spectroscopy using metal to ligand mole ratios of 1: 1 and 1: 2. In equimolar complexes, AHPDP is coordinated to palladium(II) via two phosphonic oxygen atoms, whereas AEDP is coordinated via the amino nitrogen atom and a phosphonic oxygen atom. In the bisligand palladium(II) complex with AEDP, both ligand molecules are coordinated in a bidentate mode by the amino nitrogen atom and a phosphonic oxygen atom. More... »

PAGES

1494

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0036023611040140

DOI

http://dx.doi.org/10.1134/s0036023611040140

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1038946792


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