Unusual electronic state of tin dopant atoms in surface layers of NiTiO3 View Full Text


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Article Info

DATE

2011-04

AUTHORS

R. A. Astashkin, M. V. Korolenko, M. I. Afanasov, P. B. Fabrichnyi, A. Wattiaux, C. Labrugère, C. Delmas

ABSTRACT

The 119Sn Mössbauer spectra of polycrystalline NiTiO3 samples impregnated with a solution containing 0.3 at % Sn4+ are evidence that annealing in H2 converts tin into the state with the electron density |Ψ(0)|2 on 119Sn nuclei corresponding to “Sn3+” ions. The stabilization of tin atoms in such an untypical formal oxidation state occurs at a depth of no more than 2–3 nm from the surface of titanate crystallites. It was revealed that the Sn3+ ions are not subjected to spin polarization even at temperatures considerably lower than the Néel temperature of NiTiO3, which can be explained by their location in the Ni2+ positions. The formation of Sn3+ prevents the further reduction of tin to the divalent state and, hence, precludes localization of 119Sn probe cations in positions at the interface. More... »

PAGES

606

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0036023611040048

DOI

http://dx.doi.org/10.1134/s0036023611040048

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1047740373


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