Crystal structure of osmium selenobromide OsSe2Br12 View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2011-03

AUTHORS

S. V. Volkov, P. Yu. Demchenko, L. G. Akselrud, R. E. Gladyshevskii, V. I. Pekhn’o, Z. A. Fokina, O. G. Yanko, L. B. Khar’kova

ABSTRACT

The crystal structure of the compound OsSe2Br12 obtained by the reaction of OsBr4 with SeBr4 or Se in liquid bromine at 100°C was studied by X-ray powder diffraction. The structure of osmium selenobromide corresponds to a specific type: space group C2/m, a = 14.0464(2) Å, b = 11.05398(14) Å, c = 6.50340(9) Å, β = 112.2645(11)°, Z = 2; RB = 0.03946, Rwp = 0.05403, χ2 = 4.261 for 479 reflections and 53 refinement parameters. The X-ray diffraction analysis confirmed the earlier assumption concerning the cation-anion structure of the compound representing a packing of nearly regular [OsBr6]2− octahedra as anionic complexes and deficient [:SeBr3]+ tetrahedra as cationic complexes in which the missing vertex is occupied by the lone electron pair of selenium. More... »

PAGES

387

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0036023611030272

DOI

http://dx.doi.org/10.1134/s0036023611030272

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1005113680


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