Chemical conversions of rhodium selenochloride Rh2Se9Cl6 View Full Text


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Article Info

DATE

2011-03

AUTHORS

S. V. Volkov, Yu. V. Mironov, S. S. Yarovoi, A. I. Smolentsev, O. G. Yanko, L. B. Khar’kova, Z. A. Fokina

ABSTRACT

Rhodium selenochloride Rh2Se9Cl6 (1) reacts with aqueous solutions of KCN and CsCl and 4-cyanopyridine (4-CNPy) to give complexes KCs2Rh(CN)6 (2) and RhCl3(4-CNPy)3 (3). According to X-ray diffraction data, 2 and 3 have mononuclear structures in which the rhodium atoms are in the oxidation state III and six-coordinate environment. Reactions 1 with CN-containing ligands lead to complete displacement of selenium-containing ligands from the rhodium coordination sphere. More... »

PAGES

383-386

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0036023611030260

DOI

http://dx.doi.org/10.1134/s0036023611030260

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1019788684


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