Synthesis and crystal structure of [Na(H2O)4][EuL4] · 0.775CH2Cl2 (HL = 1,3-bis(1,3-dimethyl-1H-pyrazol-4-yl)-1,3-propanedione) View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2011-03

AUTHORS

I. V. Taydakov, B. E. Zaitsev, S. S. Krasnosel’sky, I. N. Polyakova, V. S. Sergienko

ABSTRACT

[Na(H2O)4][EuL4] · 0.775CH2Cl2 (I) has been synthesized by the reaction of Eu(NO3)3 · 6H2O with 1,3-bis(1,3-dimethyl-1H-pyrasol-4-yl)-1,3-propanedione (HL) in the presence of NaOH. Its crystal structure has been solved by X-ray diffraction analysis. Crystals are tetragonal; a = 16.2401(5) Å, c = 11.9113(4) Å, V= 3141.50(17) Å3, ρcalcd = 1.427 g/cm3, μ(MoKα) = 1.140 mm−1, space group P4/n, Z = 2. The structural units forming a crystal of compound I are [EuL4]− complex anions, [Na(H2O)4]+ cations, and CH2Cl2 molecules. The coordination polyhedron of the Eu atom is an Archimedean antiprism formed by the O atoms of four bidentate chelate ligands L−. More... »

PAGES

345-349

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0036023611030211

DOI

http://dx.doi.org/10.1134/s0036023611030211

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1000085611


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