Stereoisomeric Pd(II) complexes with serine, threonine, and allothreonine View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2011-01

AUTHORS

L. F. Krylova, L. M. Kovtunova, G. V. Romanenko, L. A. Sheludyakova, N. V. Kurat’eva

ABSTRACT

The paper describes methods for the synthesis and isolation of solid phases of the individual stereoisomeric Pd(II) bis(amino acid) complexes with serine (SerH = NH2C*H(CH2OH)COOH, α-amino-β-hydroxypropionic acid), threonine (ThrH CH3C*H(OH)C*H(NH2)COOH, threo-α-amino-β-hydroxybutyric acid), and allothreonine (alloThrH is erythro-α-amino-β-hydroxybutyric acid): cis-[Pd(S-Ser)2], trans-[Pd(R-Ser)(S-Ser)], cis-[Pd(S-Thr)2], trans-[Pd(S-Thr)2], trans-[Pd(R-Thr)(S-Thr)], and cis-[Pd(R-alloThr)(S-alloThr)] (R, S are the absolute configurations of the asymmetric C* atom connected to the NH2 group). The synthesized compounds were characterized by elemental analysis, IR and NMR (1H and 13C) data, and X-ray diffraction analysis. More... »

PAGES

52-60

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0036023611010165

DOI

http://dx.doi.org/10.1134/s0036023611010165

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1029617091


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