Bis(2-alkyl-4-thiocarbamoyl-4-pyridinium) hexafluorosilicates View Full Text


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Article Info

DATE

2010-08-26

AUTHORS

V. O. Gel’mbol’dt, E. V. Ganin, L. Kh. Minacheva, L. V. Koroeva, V. S. Sergienko

ABSTRACT

The reaction of 45% silicahydrofluoric acid with 2-ethyl-4-thiocarbamoyl-4-pyridine (L1) and 2-propyl-4-thiocarbamoyl-4-pyridine (L2) yields (L1H)2SiF6 and (L2H)2SiF6 hexafluorosilicates. These hexafluorosilicates are characterized by the data of IR spectroscopy, mass spectrometry, potentiometry, and solubility. The structure of (L1H)2SiF6 is determined by X-ray diffraction. In the ionic structure of the complex, the L1H+ cations (the protonation center is the pyridinic N atom) and SiF62− anions (Si-F 1.657(2)–1.699(2) Å) are joined by a system of interionic hydrogen bonds NH⋯F. Correlation between the characteristics of the interionic hydrogen bonds and the solubility of the hexafluorosilicates is discussed. More... »

PAGES

1209-1215

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0036023610080097

DOI

http://dx.doi.org/10.1134/s0036023610080097

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1037107012


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