Synthesis and X-ray diffraction study of R[UO2(CH3COO)3] (R = H3O+ or NH(C2H5)3+) View Full Text


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Article Info

DATE

2010-07

AUTHORS

L. B. Serezhkina, E. V. Peresypkina, A. V. Virovets, N. A. Neklyudova

ABSTRACT

Single crystals of (H3O)[UO2(CH3COO)3] (I) and (NH(C2H5)3)[UO2(CH3COO)3] (II) are synthesized, and their structures are studied by X-ray crystallography. Compound I crystallizes in the tetragonal crystal system with the unit cell parameters a = 13.70640(10) Å, c = 27.5258(5) Å, V = 5171.14(11) Å3, space group I41/a, Z = 16, R = 0.0238. The crystals of compound II are orthorhombic with the parameters a = 13.3685(3) Å, b = 10.6990(3) Å, c = 12.2616(3) Å, V = 1753.77(8) Å3, space group Pna21, Z = 4, R = 0.0228. The uranium-containing structural units of crystals I and II are [UO2(CH3COO)3]− island mononuclear groups belonging to the A B301(A = UO22+, B01 = CH3COO−) crystal-chemical group of uranyl complexes. [UO2(CH3COO)3]− complexes are linked into a three-dimensional framework by electrostatic interactions with the outer-sphere cations and by hydrogen bonds involving the hydrogen atoms of hydroxonium (I) or triethylammonium (II) with the oxygen atoms of the acetato groups. More... »

PAGES

1020-1025

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0036023610070065

DOI

http://dx.doi.org/10.1134/s0036023610070065

DIMENSIONS

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