Spectrophotometric studies of alkali and alkali earth metal ions complexes of mono amino derivative of calix[4]arene View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2010-03

AUTHORS

Farrokh Gharib, Noushin Osouleddini, Karim Zare, Saeed Taghvaei-Ganjali

ABSTRACT

The synthesis and complexive abilities of 5,11,17-tris(tert-butyl)-23 amino-25,26,27,28-tetra-propoxycalix[4]arene towards alkali cations Li+, Na+, K+, Rb+, Cs+ and alkali earth cations Mg2+, Ca2+, Sr2+ and Ba2+ in methanol-chloroform mixture have been evaluated at 25°C, using UV-Vis spectrophotometric techniques. The results showed that the ligand is capable to complex with all the cations by 1: 1 metal to ligand ratios. The selectivity presented considering the calculated formation constants are in the order Li+ > Na+ > K+ > Rb+ > Cs+ and Mg2+ > Ca2+ > Sr2+ > Ba2+ with the ligand. More... »

PAGES

434-437

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s003602361003023x

DOI

http://dx.doi.org/10.1134/s003602361003023x

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1051027690


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