Crystal structure and spectral characteristics of Bis(1-adamantyl acetoacetato)copper(II) View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2009-12

AUTHORS

L. I. Koval, E. B. Rusanov, E. L. Ilnitska, V. I. Dzyuba, V. I. Pekhnyo

ABSTRACT

The structure of a new complex bis(1-adamantyl acetoacetato)copper(II) was studied by X-ray crystallography, electronic absorption spectroscopy in the visible, and vibrational spectroscopy. Copper atoms have a square coordination in both solutions and crystals. The crystals are triclinic, space group P, a = 6.9389(6) Å, b = 9.0697(8) Å, c = 11.4280(10) Å, α = 109.279(4) °, β = 100.179(4)°, γ = 98.171(4)°, V = 652.45(10) Å3, Z = 2. Molecules form the crystals only due to van der Waals forces, because Cu-C intermolecular interactions, which are characteristic of other β-dicarbonyl complexes of copper(II), are absent. More... »

PAGES

1931

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0036023609120158

DOI

http://dx.doi.org/10.1134/s0036023609120158

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1010817304


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