Crystal structure of Cs[(UO2)2(C2O4)2(OH)] · H2O View Full Text


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Article Info

DATE

2009-10

AUTHORS

L. B. Serezhkina, E. V. Peresypkina, A. V. Virovets, I. V. Medrish, D. V. Pushkin

ABSTRACT

Single crystals of Cs[(UO2)2(C2O4)2(OH)] · H2O were synthesized and structurally studied using X-ray diffraction. The compound crystallizes in monoclinic space group P21/m, Z = 2, with the unit cell parameters a = 5.5032(4) Å, b = 13.5577(8) Å, c = 9.5859(8) Å, β = 97.012(3)°, V = 709.86(9) Å3, R = 0.0444. The main building units of crystals are [(UO2)2(C2O4)2(OH)]− layers of the A2K202M2 (A = UO22+, K02 = C2O42−, and M2 = OH−) crystal-chemical family. Uranium-containing layers are linked into a three-dimensional framework via electrostatic interactions with outer-sphere cations and hydrogen bonds with water molecules. More... »

PAGES

1577

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0036023609100131

DOI

http://dx.doi.org/10.1134/s0036023609100131

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1048724470


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