Synthesis, crystal and molecular structure of tetraaquabis(nicotinamide)cobalt(II) phthalate dihydrate View Full Text


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Article Info

DATE

2009-08

AUTHORS

A. S. Antsyshkina, G. G. Sadikov, T. V. Koksharova, I. S. Gritsenko, V. S. Sergienko

ABSTRACT

The coordination compound of cobalt(II) with nicotinamide [CoL2(H2O)4][C6H4(COO)2] · 2H2O (I) (where L stands for nicotinamide) was synthesized and characterized by IR spectroscopy, conductometry, and thermogravimetry. The X-ray structure of complex I was determined. Crystals are monoclinic: a = 15.630(2) Å, b = 7.550(2) Å, c = 21.035(4) Å, β = 100.90(5)°, V = 2437.4(4) Å3, Z = 4, space group C2/c. The structural units of complex I are centrosymmetrical cations [CoL2(H2O)4]2+, anions [C6H4(COO)2]2− (lying on axis 2), and molecules of waster of crystallization. Complex cations are packed into layers are alternate with layers containing anions and free H2O molecules. This is a classical case of π-π-staking interactions that lead to the formation of supramolecular layered assemblies. More... »

PAGES

1310-1315

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s003602360908021x

DOI

http://dx.doi.org/10.1134/s003602360908021x

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1016114490


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