[Co2(NH2CH2CH2O)3(NH2CH2CH2OH)3][CoCl4]Cl · H2O: Synthesis and crystal structure View Full Text


Ontology type: schema:ScholarlyArticle      Open Access: True


Article Info

DATE

2009-04

AUTHORS

Yu. A. Mikhailenko, E. V. Peresypkina, A. V. Virovets, T. G. Cherkasova

ABSTRACT

A new complex of ethanolamine with mixed-valence cobalt of the composition [CoIII(EtaH)2(Eta)][CoIII(EtaH)(Eta)2][CoIICl4]Cl · H2O, where EtaH is monoethanolamine NH2(CH2)2OH, is synthesized and structurally characterized. The crystals are monoclinic: a = 8.7451(2), b = 14.5009(4), c = 22.1663(5) Å, β = 91.3000(10)°, V = 2810.23(12) Å3, Z = 4, ρcalcd = 1.739 g/cm3, R = 0.0316 for 6531 reflections (Fo ≥ 4σ(F)). The structure contains two complex cations [Co(EtaH)2(Eta)]2+ and [Co(EtaH)(Eta)2]+ linked by short hydrogen bonds. More... »

PAGES

568-571

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0036023609040135

DOI

http://dx.doi.org/10.1134/s0036023609040135

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1024697428


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0601", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Biochemistry and Cell Biology", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/06", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Biological Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Kuzbass State Technical University", 
          "id": "https://www.grid.ac/institutes/grid.445327.3", 
          "name": [
            "Kuzbass State Technical University, Kemerovo, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Mikhailenko", 
        "givenName": "Yu. A.", 
        "id": "sg:person.011623266445.40", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011623266445.40"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Nikolaev Institute of Inorganic Chemistry", 
          "id": "https://www.grid.ac/institutes/grid.425759.8", 
          "name": [
            "Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, pr. Akad. Lavrent\u2019eva 3, 630090, Novosibirsk, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Peresypkina", 
        "givenName": "E. V.", 
        "id": "sg:person.0623032534.48", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0623032534.48"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Nikolaev Institute of Inorganic Chemistry", 
          "id": "https://www.grid.ac/institutes/grid.425759.8", 
          "name": [
            "Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, pr. Akad. Lavrent\u2019eva 3, 630090, Novosibirsk, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Virovets", 
        "givenName": "A. V.", 
        "id": "sg:person.0642271552.29", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0642271552.29"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Kuzbass State Technical University", 
          "id": "https://www.grid.ac/institutes/grid.445327.3", 
          "name": [
            "Kuzbass State Technical University, Kemerovo, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Cherkasova", 
        "givenName": "T. G.", 
        "id": "sg:person.011270210671.85", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011270210671.85"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1107/s0108768102003890", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1012549006"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/dt9860000651", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1045693258"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/zaac.19412480404", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1046714512"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0022-2860(02)00105-9", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1047544172"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0020-1693(00)89885-0", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1051301564"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja01037a047", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055763184"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2009-04", 
    "datePublishedReg": "2009-04-01", 
    "description": "A new complex of ethanolamine with mixed-valence cobalt of the composition [CoIII(EtaH)2(Eta)][CoIII(EtaH)(Eta)2][CoIICl4]Cl \u00b7 H2O, where EtaH is monoethanolamine NH2(CH2)2OH, is synthesized and structurally characterized. The crystals are monoclinic: a = 8.7451(2), b = 14.5009(4), c = 22.1663(5) \u00c5, \u03b2 = 91.3000(10)\u00b0, V = 2810.23(12) \u00c53, Z = 4, \u03c1calcd = 1.739 g/cm3, R = 0.0316 for 6531 reflections (Fo \u2265 4\u03c3(F)). The structure contains two complex cations [Co(EtaH)2(Eta)]2+ and [Co(EtaH)(Eta)2]+ linked by short hydrogen bonds.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1134/s0036023609040135", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": true, 
    "isPartOf": [
      {
        "id": "sg:journal.1004031", 
        "issn": [
          "0036-0236", 
          "0044-457X"
        ], 
        "name": "Russian Journal of Inorganic Chemistry", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "4", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "54"
      }
    ], 
    "name": "[Co2(NH2CH2CH2O)3(NH2CH2CH2OH)3][CoCl4]Cl \u00b7 H2O: Synthesis and crystal structure", 
    "pagination": "568-571", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "75a8d69759fabacd7cf44e61c2fa04fd3ac824029c6a943d47935b1087605afa"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1134/s0036023609040135"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1024697428"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1134/s0036023609040135", 
      "https://app.dimensions.ai/details/publication/pub.1024697428"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-11T09:08", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000338_0000000338/records_47960_00000000.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1134/S0036023609040135"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s0036023609040135'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s0036023609040135'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s0036023609040135'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s0036023609040135'


 

This table displays all metadata directly associated to this object as RDF triples.

103 TRIPLES      21 PREDICATES      33 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1134/s0036023609040135 schema:about anzsrc-for:06
2 anzsrc-for:0601
3 schema:author N853c2ccf25bb422e887942acbb669a0d
4 schema:citation https://doi.org/10.1002/zaac.19412480404
5 https://doi.org/10.1016/s0020-1693(00)89885-0
6 https://doi.org/10.1016/s0022-2860(02)00105-9
7 https://doi.org/10.1021/ja01037a047
8 https://doi.org/10.1039/dt9860000651
9 https://doi.org/10.1107/s0108768102003890
10 schema:datePublished 2009-04
11 schema:datePublishedReg 2009-04-01
12 schema:description A new complex of ethanolamine with mixed-valence cobalt of the composition [CoIII(EtaH)2(Eta)][CoIII(EtaH)(Eta)2][CoIICl4]Cl · H2O, where EtaH is monoethanolamine NH2(CH2)2OH, is synthesized and structurally characterized. The crystals are monoclinic: a = 8.7451(2), b = 14.5009(4), c = 22.1663(5) Å, β = 91.3000(10)°, V = 2810.23(12) Å3, Z = 4, ρcalcd = 1.739 g/cm3, R = 0.0316 for 6531 reflections (Fo ≥ 4σ(F)). The structure contains two complex cations [Co(EtaH)2(Eta)]2+ and [Co(EtaH)(Eta)2]+ linked by short hydrogen bonds.
13 schema:genre research_article
14 schema:inLanguage en
15 schema:isAccessibleForFree true
16 schema:isPartOf N64b7f7a0b9414117a32d6660bf5b8bc7
17 Nbab89fc3a579436482defd47ba8dba53
18 sg:journal.1004031
19 schema:name [Co2(NH2CH2CH2O)3(NH2CH2CH2OH)3][CoCl4]Cl · H2O: Synthesis and crystal structure
20 schema:pagination 568-571
21 schema:productId Nb0a2f693ff2c47f9bc95f4f33bad1af7
22 Nbc2689249dd6483a8a57d2debfe92e30
23 Nca3cea3316bd4f4a9cfc45e0d2cdceff
24 schema:sameAs https://app.dimensions.ai/details/publication/pub.1024697428
25 https://doi.org/10.1134/s0036023609040135
26 schema:sdDatePublished 2019-04-11T09:08
27 schema:sdLicense https://scigraph.springernature.com/explorer/license/
28 schema:sdPublisher N93cebd76bcf14cf5bb7c1fc30917de2e
29 schema:url http://link.springer.com/10.1134/S0036023609040135
30 sgo:license sg:explorer/license/
31 sgo:sdDataset articles
32 rdf:type schema:ScholarlyArticle
33 N083797eaeb0b41918ed6632a82c1a38a rdf:first sg:person.011270210671.85
34 rdf:rest rdf:nil
35 N320d6ac2949444fb9b4a02cb022d50b9 rdf:first sg:person.0642271552.29
36 rdf:rest N083797eaeb0b41918ed6632a82c1a38a
37 N4c1f5ee3b2224d848af4173fce08a4dc rdf:first sg:person.0623032534.48
38 rdf:rest N320d6ac2949444fb9b4a02cb022d50b9
39 N64b7f7a0b9414117a32d6660bf5b8bc7 schema:issueNumber 4
40 rdf:type schema:PublicationIssue
41 N853c2ccf25bb422e887942acbb669a0d rdf:first sg:person.011623266445.40
42 rdf:rest N4c1f5ee3b2224d848af4173fce08a4dc
43 N93cebd76bcf14cf5bb7c1fc30917de2e schema:name Springer Nature - SN SciGraph project
44 rdf:type schema:Organization
45 Nb0a2f693ff2c47f9bc95f4f33bad1af7 schema:name doi
46 schema:value 10.1134/s0036023609040135
47 rdf:type schema:PropertyValue
48 Nbab89fc3a579436482defd47ba8dba53 schema:volumeNumber 54
49 rdf:type schema:PublicationVolume
50 Nbc2689249dd6483a8a57d2debfe92e30 schema:name readcube_id
51 schema:value 75a8d69759fabacd7cf44e61c2fa04fd3ac824029c6a943d47935b1087605afa
52 rdf:type schema:PropertyValue
53 Nca3cea3316bd4f4a9cfc45e0d2cdceff schema:name dimensions_id
54 schema:value pub.1024697428
55 rdf:type schema:PropertyValue
56 anzsrc-for:06 schema:inDefinedTermSet anzsrc-for:
57 schema:name Biological Sciences
58 rdf:type schema:DefinedTerm
59 anzsrc-for:0601 schema:inDefinedTermSet anzsrc-for:
60 schema:name Biochemistry and Cell Biology
61 rdf:type schema:DefinedTerm
62 sg:journal.1004031 schema:issn 0036-0236
63 0044-457X
64 schema:name Russian Journal of Inorganic Chemistry
65 rdf:type schema:Periodical
66 sg:person.011270210671.85 schema:affiliation https://www.grid.ac/institutes/grid.445327.3
67 schema:familyName Cherkasova
68 schema:givenName T. G.
69 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011270210671.85
70 rdf:type schema:Person
71 sg:person.011623266445.40 schema:affiliation https://www.grid.ac/institutes/grid.445327.3
72 schema:familyName Mikhailenko
73 schema:givenName Yu. A.
74 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011623266445.40
75 rdf:type schema:Person
76 sg:person.0623032534.48 schema:affiliation https://www.grid.ac/institutes/grid.425759.8
77 schema:familyName Peresypkina
78 schema:givenName E. V.
79 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0623032534.48
80 rdf:type schema:Person
81 sg:person.0642271552.29 schema:affiliation https://www.grid.ac/institutes/grid.425759.8
82 schema:familyName Virovets
83 schema:givenName A. V.
84 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0642271552.29
85 rdf:type schema:Person
86 https://doi.org/10.1002/zaac.19412480404 schema:sameAs https://app.dimensions.ai/details/publication/pub.1046714512
87 rdf:type schema:CreativeWork
88 https://doi.org/10.1016/s0020-1693(00)89885-0 schema:sameAs https://app.dimensions.ai/details/publication/pub.1051301564
89 rdf:type schema:CreativeWork
90 https://doi.org/10.1016/s0022-2860(02)00105-9 schema:sameAs https://app.dimensions.ai/details/publication/pub.1047544172
91 rdf:type schema:CreativeWork
92 https://doi.org/10.1021/ja01037a047 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055763184
93 rdf:type schema:CreativeWork
94 https://doi.org/10.1039/dt9860000651 schema:sameAs https://app.dimensions.ai/details/publication/pub.1045693258
95 rdf:type schema:CreativeWork
96 https://doi.org/10.1107/s0108768102003890 schema:sameAs https://app.dimensions.ai/details/publication/pub.1012549006
97 rdf:type schema:CreativeWork
98 https://www.grid.ac/institutes/grid.425759.8 schema:alternateName Nikolaev Institute of Inorganic Chemistry
99 schema:name Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, pr. Akad. Lavrent’eva 3, 630090, Novosibirsk, Russia
100 rdf:type schema:Organization
101 https://www.grid.ac/institutes/grid.445327.3 schema:alternateName Kuzbass State Technical University
102 schema:name Kuzbass State Technical University, Kemerovo, Russia
103 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...