Synthesis, structure, physicochemical properties, and solid-phase thermolysis of Co2Sm(Piv)7(2,4-Lut)2 View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2009-04

AUTHORS

M. A. Bykov, A. L. Emelina, E. V. Orlova, M. A. Kiskin, G. G. Aleksandrov, A. S. Bogomyakov, Zh. V. Dobrokhotova, V. M. Novotortsev, I. L. Eremenko

ABSTRACT

Heterometallic pivalate Co2Sm(Piv)7(2,4-Lut)2 (1) was prepared for the first time and structurally characterized at 293 and 160 K. Antiferromagnetic exchange interactions are dominant in complex 1. This compound experiences a first-order phase transition within 210–260 K. A set of thermodynamic functions was obtained for this complex (Cp, HT0 - H1800, and ST0), and parameters were determined for solid-phase thermolysis where samarium cobaltate SmCoO3 is the only product. More... »

PAGES

548-557

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s003602360904010x

DOI

http://dx.doi.org/10.1134/s003602360904010x

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1008571767


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