Tetraaquatetrakis(ɛ-caprolactam)lutetium(III) hexaisothiocyanatochromate(III) sesquihydrate View Full Text


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Article Info

DATE

2009-02

AUTHORS

E. V. Cherkasova, A. V. Virovets, E. V. Peresypkina, T. G. Cherkasova

ABSTRACT

The ionic complex [Lu(ɛ-C6H11NO)4(H2O)4][Cr(NCS)6] · 1.5H2O, the first example of coordination of ɛ-caprolactam to the lutetium atom, was synthesized by the reaction of Lu(NO3)3, K3[Cr(NCS)6], and ɛ-caprolactam in an aqueous solution. The structure of the complex was established by IR spectroscopy and X-ray crystallography. The crystals are triclinic, space group PT = 100 K, a = 11.9604(3) Å, b = 12.3640(3) Å, c = 18.3506(5) Å, α = 91.3200(10)°, β = 108.6640(10)°, γ = 112.4460(10)°, V = 2343.45(10) Å3, Z = 2, ρcalcd = 1.597 g/cm3, R = 0.0299 for 9839 reflections with Fhkl≥4σ(F). The coordination polyhedron of the lutetium atom is a distorted square antiprism with broken square faces with the oxygen atoms of the organic ligands and water at the vertices. There are weak intramolecular hydrogen bonds N-H…O(H2) in the cation. The coordination polyhedron of the chromium atom is a somewhat distorted octahedron. The thermal stability of the compound was studied in an inert atmosphere and in air. More... »

PAGES

272-276

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0036023609020181

DOI

http://dx.doi.org/10.1134/s0036023609020181

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1022776104


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