119Sn Mössbauer study of the influence of a gas atmosphere on the valence state and distribution of tin atoms in ... View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2008-08

AUTHORS

M. I. Afanasov, P. B. Fabrichnyi, M. V. Korolenko, T. M. Ivanova

ABSTRACT

Analysis of the Mössbauer spectra of dopant 119Sn in cubic MgO has demonstrated that the Sn2+ ions can be stabilized on the surface of crystallites of an oxide with a structure differing from the corundum structure. The Mössbauer parameters (at 100 K, the isomer shift is δ = 2.50 ± 0.01 mm/s and the quadrupole splitting is Δ = 2.30 ± 0.02 mm/s) point to the stereochemical activity of the lone pair of Sn2+. Being in contact with oxygen at 295 K, tin is rapidly converted to the tetravalent state (δ = 0.08 ± 0.01 mms, Δ = 0.58 ± 0.01 mm/s). The lack of formation of Sn2+ on the surface of another cubic oxide (MnO) can be explained by rapid segregation of tin from the bulk of crystallites as stannate clusters. More... »

PAGES

1288-1291

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0036023608080226

DOI

http://dx.doi.org/10.1134/s0036023608080226

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1027560906


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Moscow State University", 
          "id": "https://www.grid.ac/institutes/grid.14476.30", 
          "name": [
            "Moscow State University, 119992, Leninskie gory, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Afanasov", 
        "givenName": "M. I.", 
        "id": "sg:person.013436616565.34", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013436616565.34"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Moscow State University", 
          "id": "https://www.grid.ac/institutes/grid.14476.30", 
          "name": [
            "Moscow State University, 119992, Leninskie gory, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Fabrichnyi", 
        "givenName": "P. B.", 
        "id": "sg:person.014167176071.01", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014167176071.01"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Moscow State University", 
          "id": "https://www.grid.ac/institutes/grid.14476.30", 
          "name": [
            "Moscow State University, 119992, Leninskie gory, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Korolenko", 
        "givenName": "M. V.", 
        "id": "sg:person.016163514462.70", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016163514462.70"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Moscow State University", 
          "id": "https://www.grid.ac/institutes/grid.14476.30", 
          "name": [
            "Moscow State University, 119992, Leninskie gory, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Ivanova", 
        "givenName": "T. M.", 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.2183/pjab.55.43", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1036446693"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1088/0370-1328/79/2/323", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1059094395"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2008-08", 
    "datePublishedReg": "2008-08-01", 
    "description": "Analysis of the M\u00f6ssbauer spectra of dopant 119Sn in cubic MgO has demonstrated that the Sn2+ ions can be stabilized on the surface of crystallites of an oxide with a structure differing from the corundum structure. The M\u00f6ssbauer parameters (at 100 K, the isomer shift is \u03b4 = 2.50 \u00b1 0.01 mm/s and the quadrupole splitting is \u0394 = 2.30 \u00b1 0.02 mm/s) point to the stereochemical activity of the lone pair of Sn2+. Being in contact with oxygen at 295 K, tin is rapidly converted to the tetravalent state (\u03b4 = 0.08 \u00b1 0.01 mms, \u0394 = 0.58 \u00b1 0.01 mm/s). The lack of formation of Sn2+ on the surface of another cubic oxide (MnO) can be explained by rapid segregation of tin from the bulk of crystallites as stannate clusters.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1134/s0036023608080226", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1004031", 
        "issn": [
          "0036-0236", 
          "0044-457X"
        ], 
        "name": "Russian Journal of Inorganic Chemistry", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "8", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "53"
      }
    ], 
    "name": "119Sn M\u00f6ssbauer study of the influence of a gas atmosphere on the valence state and distribution of tin atoms in the MgO structure", 
    "pagination": "1288-1291", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "834ad6aa5dd84a72d57237996ac448ad85c1333601bdb7498f836e6dc2099d3c"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1134/s0036023608080226"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1027560906"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1134/s0036023608080226", 
      "https://app.dimensions.ai/details/publication/pub.1027560906"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-10T14:08", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8660_00000505.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1134/S0036023608080226"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s0036023608080226'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s0036023608080226'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s0036023608080226'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s0036023608080226'


 

This table displays all metadata directly associated to this object as RDF triples.

87 TRIPLES      21 PREDICATES      29 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1134/s0036023608080226 schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author Nb1a68ad934ff4385a4908d9287a408ad
4 schema:citation https://doi.org/10.1088/0370-1328/79/2/323
5 https://doi.org/10.2183/pjab.55.43
6 schema:datePublished 2008-08
7 schema:datePublishedReg 2008-08-01
8 schema:description Analysis of the Mössbauer spectra of dopant 119Sn in cubic MgO has demonstrated that the Sn2+ ions can be stabilized on the surface of crystallites of an oxide with a structure differing from the corundum structure. The Mössbauer parameters (at 100 K, the isomer shift is δ = 2.50 ± 0.01 mm/s and the quadrupole splitting is Δ = 2.30 ± 0.02 mm/s) point to the stereochemical activity of the lone pair of Sn2+. Being in contact with oxygen at 295 K, tin is rapidly converted to the tetravalent state (δ = 0.08 ± 0.01 mms, Δ = 0.58 ± 0.01 mm/s). The lack of formation of Sn2+ on the surface of another cubic oxide (MnO) can be explained by rapid segregation of tin from the bulk of crystallites as stannate clusters.
9 schema:genre research_article
10 schema:inLanguage en
11 schema:isAccessibleForFree false
12 schema:isPartOf Nc8856fd0009941f1bdfb94c45442cdbc
13 Nfee45eb9fae447128c9bc01123ab0156
14 sg:journal.1004031
15 schema:name 119Sn Mössbauer study of the influence of a gas atmosphere on the valence state and distribution of tin atoms in the MgO structure
16 schema:pagination 1288-1291
17 schema:productId N3f26d0bd852f44dbb099daa2ca6f3daa
18 N4a230b79b9bf4f0eab4ca9970f9d2bbe
19 Nca1eab6b71534b8ba9188ea21cd5c0d2
20 schema:sameAs https://app.dimensions.ai/details/publication/pub.1027560906
21 https://doi.org/10.1134/s0036023608080226
22 schema:sdDatePublished 2019-04-10T14:08
23 schema:sdLicense https://scigraph.springernature.com/explorer/license/
24 schema:sdPublisher N8c077567851f43748c48ad3dc03d2089
25 schema:url http://link.springer.com/10.1134/S0036023608080226
26 sgo:license sg:explorer/license/
27 sgo:sdDataset articles
28 rdf:type schema:ScholarlyArticle
29 N1c6e1f96a79d45cd8fec1e4a83ace7aa rdf:first sg:person.016163514462.70
30 rdf:rest Nf8ceb035f69649a79f4696a2526a9b95
31 N3f26d0bd852f44dbb099daa2ca6f3daa schema:name readcube_id
32 schema:value 834ad6aa5dd84a72d57237996ac448ad85c1333601bdb7498f836e6dc2099d3c
33 rdf:type schema:PropertyValue
34 N4a230b79b9bf4f0eab4ca9970f9d2bbe schema:name dimensions_id
35 schema:value pub.1027560906
36 rdf:type schema:PropertyValue
37 N8c077567851f43748c48ad3dc03d2089 schema:name Springer Nature - SN SciGraph project
38 rdf:type schema:Organization
39 Nb1a68ad934ff4385a4908d9287a408ad rdf:first sg:person.013436616565.34
40 rdf:rest Ndc88e98fc9da4b278ea31f4956a8be5a
41 Nbe7884630ec94d9cb8606612f08757bc schema:affiliation https://www.grid.ac/institutes/grid.14476.30
42 schema:familyName Ivanova
43 schema:givenName T. M.
44 rdf:type schema:Person
45 Nc8856fd0009941f1bdfb94c45442cdbc schema:issueNumber 8
46 rdf:type schema:PublicationIssue
47 Nca1eab6b71534b8ba9188ea21cd5c0d2 schema:name doi
48 schema:value 10.1134/s0036023608080226
49 rdf:type schema:PropertyValue
50 Ndc88e98fc9da4b278ea31f4956a8be5a rdf:first sg:person.014167176071.01
51 rdf:rest N1c6e1f96a79d45cd8fec1e4a83ace7aa
52 Nf8ceb035f69649a79f4696a2526a9b95 rdf:first Nbe7884630ec94d9cb8606612f08757bc
53 rdf:rest rdf:nil
54 Nfee45eb9fae447128c9bc01123ab0156 schema:volumeNumber 53
55 rdf:type schema:PublicationVolume
56 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
57 schema:name Chemical Sciences
58 rdf:type schema:DefinedTerm
59 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
60 schema:name Physical Chemistry (incl. Structural)
61 rdf:type schema:DefinedTerm
62 sg:journal.1004031 schema:issn 0036-0236
63 0044-457X
64 schema:name Russian Journal of Inorganic Chemistry
65 rdf:type schema:Periodical
66 sg:person.013436616565.34 schema:affiliation https://www.grid.ac/institutes/grid.14476.30
67 schema:familyName Afanasov
68 schema:givenName M. I.
69 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013436616565.34
70 rdf:type schema:Person
71 sg:person.014167176071.01 schema:affiliation https://www.grid.ac/institutes/grid.14476.30
72 schema:familyName Fabrichnyi
73 schema:givenName P. B.
74 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014167176071.01
75 rdf:type schema:Person
76 sg:person.016163514462.70 schema:affiliation https://www.grid.ac/institutes/grid.14476.30
77 schema:familyName Korolenko
78 schema:givenName M. V.
79 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016163514462.70
80 rdf:type schema:Person
81 https://doi.org/10.1088/0370-1328/79/2/323 schema:sameAs https://app.dimensions.ai/details/publication/pub.1059094395
82 rdf:type schema:CreativeWork
83 https://doi.org/10.2183/pjab.55.43 schema:sameAs https://app.dimensions.ai/details/publication/pub.1036446693
84 rdf:type schema:CreativeWork
85 https://www.grid.ac/institutes/grid.14476.30 schema:alternateName Moscow State University
86 schema:name Moscow State University, 119992, Leninskie gory, Moscow, Russia
87 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...