Synthesis and structure of (NH4)2[(UO2)2(C2O4)(CH3COO)4] · 2H2O View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2008-08

AUTHORS

L. B. Serezhkina, A. V. Vologzhanina, N. A. Neklyudova, V. N. Serezhkin, M. Yu. Antipin

ABSTRACT

Single crystals of (NH4)2[(UO2)2C2O4(CH3COO)4] · 2H2O have been synthesized and studied. The compound crystallizes in the orthorhombic system with the unit cell parameters a = 6.9225(14) Å, b = 12.327(3) Å, c = 14.619(3) Å, space group Immm, Z = 2, and V = 1247.6(5) Å3. The main structural units of the crystals are the isle binuclear groups [(UO2)2C2O4(CH3COO)4]2− belonging to the crystal-chemical group A2K02B401 (A = UO22+, K02 = C2O42−, B01 = CH3COO−) of the uranyl complexes. The uranium-containing groups are linked into a three-dimensional framework due to electrostatic interaction with the ammonium cations and through a system of hydrogen bonds involving atoms of the water molecules, oxalate and acetate ions, and ammonium and uranyl cations. More... »

PAGES

1193-1196

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s003602360808007x

DOI

http://dx.doi.org/10.1134/s003602360808007x

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1024272181


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