The directional polymeric chain of [(BiCl5)2−]n in 2,2′-Bi(2-1H-imidazolium) pentachlorobismuthate dihydrate View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2008-04

AUTHORS

Zhi-Min Jin, Hai Yang Li, Hai Bin Wang, Wen Jie Feng

ABSTRACT

The title compound, (C6H6N4)(BiCl5) · 2H2O, is built up by 2,2′-bi(2-1H-imidazolium) dications and (BiCl5)2− anions. Distorted BiCl6 octahedra are joined with each other alternatively to form [(BiCl5)2−]n polymeric chains, where the bridging chlorine atoms are shared by two octahedra. The lone pair at the Bi atom shows obviously stereochemical activity, leading to distortion of the BiCl6 octahedra and formation of the chain directionality. In solid state, the chains are stabilized by O-H···Cl and C-H···Cl hydrogen bonds. More... »

PAGES

594-597

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0036023608040190

DOI

http://dx.doi.org/10.1134/s0036023608040190

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1032177529


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