Synthesis and crystal structures of tetraacetylethylenediamine and N-(2-ammoniumethyl)carbamate View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2007-10

AUTHORS

A. S. Antsyshkina, G. G. Sadikov, I. A. Solonina, M. N. Rodnikova

ABSTRACT

Two ethylenediamine derivatives—N-(2-ammoniumethyl)carbamate HN(COO−)CH2CH2N+H3 (I) and tetraacetylethylenediamine (H3CC(O))2NCH2CH2N(C(O)CH3)2 (II) (synthesized for the first time)—have been synthesized and characterized by X-ray crystallography. Compounds I and II are isolated as minor admixtures upon an attempt to synthesize ethylenediamine complexes of lanthanum and neodymium nitrates, respectively. The crystals of I and II are monoclinic: a = 7.778 Å, b = 8.060 Å, c = 7.568 Å, β = 95.73°, Z = 4, space group P21/c (I); a = 5.946, b = 10.255, c = 9.343 Å, β = 95.72°, Z = 2, space group P21/c (II). The bond lengths and bond angles lie within the corresponding standard values. Compounds I and II have different conformations of the N-C-C-N ethylenediamine moiety: gauche in I and trans in II, and the corresponding torsion angles are equal to 66.6° and 180°, respectively. More... »

PAGES

1561-1566

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0036023607100154

DOI

http://dx.doi.org/10.1134/s0036023607100154

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1000097336


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