Synthesis and spectral characteristics of ruthenium(III), rhodium(III), and palladium(II) complexes with 2-(3-pyridylmethyliminomethyl)phenol View Full Text


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Article Info

DATE

2007-03

AUTHORS

V. I. Pekhn’o, V. V. Bon’, S. I. Orysyk, S. V. Volkov

ABSTRACT

New Ru(III), Rh(III), and Pd(II) complexes with the ambident ligand 2-(3-pyridylmethyliminomethyl)phenol have been synthesized and characterized by electronic absorption and IR spectroscopy, 1H NMR, and elemental analysis and electrophoresis methods. The synthesis conditions and the nature of the metal turn out to have an effect on the coordination mode of the ligand in the resulting complexes. The existence of the intramolecular hydrogen bond in the ligand molecule is favorable for its coordination in the molecular form to the complex-forming metal. More... »

PAGES

359-366

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0036023607030114

DOI

http://dx.doi.org/10.1134/s0036023607030114

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1022031207


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