Synthesis and crystal structure of divaleratobis(nicotinamide)copper(II) View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2006-10

AUTHORS

A. S. Antsyshkina, G. G. Sadikov, T. V. Koksharova, I. S. Gritsenko, V. S. Sergienko

ABSTRACT

A copper(II) valerate complex with nicotinamide (L) [CuL2(C4H9COO)2] (I) has been synthesized and studied by IR spectroscopy and thermogravimetry. The crystal structure has been determined. The crystals of 1 are monoclinic, a = 11.297(1) Å, b = 6.666(1) Å, c = 16.873(2) Å, b = 108.50(1)°, V = 1204.9(3) Å3, Z = 2, space group P21/c. The structural units of the crystal of I are centrosymmetric tetragonal bipyramidal (4+2) complex molecules. The equatorial positions of the bipyramid are occupied by trans-arranged pairs of O (Cu-O, 1.973 Å) and N (Cu-N, 2.006 Å) atoms, and the axial positions are occupied by the second O atoms of the valerate anions located at longer distances (Cu-O, 2.506 Å). The supramolecular associates formed in the crystal are layers of hydrogen-bonded complexes. The disordered hydrocarbon “tails” of the valerate groups point toward the interlayer space. More... »

PAGES

1571-1576

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s003602360610010x

DOI

http://dx.doi.org/10.1134/s003602360610010x

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1022853890


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