Crystal structure of p-nitroanilinium hexafluorosilicate View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2006-10

AUTHORS

V. O. Gel’mbol’dt, L. Kh. Minacheva, E. V. Ganin, V. S. Sergienko

ABSTRACT

Complex (p-O2NC6H4NH3)2SiF6 (I) is prepared by reacting fluorostlicic acid with p-nitroaniline in methanol and structurally studied using single-crystal X-ray diffraction. In the ionic structure of this complex, SiF62− centrosymmetrical anions (avg. Si-F, 1.671(3) Å) and O2NC6H4NH3+ cations are linked through NH…F interionic H-bonds (N…F 2.823(5)-3.205(7) Å). The thermochemical features of complex I are discussed in light of the structure data. More... »

PAGES

1561-1564

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0036023606100081

DOI

http://dx.doi.org/10.1134/s0036023606100081

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1031948780


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Physicochemical Institute of Environmental and Human Protection, Ministry of Education and Science of Ukraine and National Academy of Sciences of Ukraine, Preobrazhenskaya ul. 3, 65082, Odessa, Ukraine", 
          "id": "http://www.grid.ac/institutes/grid.418751.e", 
          "name": [
            "Physicochemical Institute of Environmental and Human Protection, Ministry of Education and Science of Ukraine and National Academy of Sciences of Ukraine, Preobrazhenskaya ul. 3, 65082, Odessa, Ukraine"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Gel\u2019mbol\u2019dt", 
        "givenName": "V. O.", 
        "id": "sg:person.013621052757.70", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013621052757.70"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr 31, 119991, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/grid.435216.7", 
          "name": [
            "Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr 31, 119991, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Minacheva", 
        "givenName": "L. Kh.", 
        "id": "sg:person.016003603003.53", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016003603003.53"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Odessa State Ecological University, Lvovskaya ul., 15, 65016, Odessa, Ukraine", 
          "id": "http://www.grid.ac/institutes/None", 
          "name": [
            "Odessa State Ecological University, Lvovskaya ul., 15, 65016, Odessa, Ukraine"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Ganin", 
        "givenName": "E. V.", 
        "id": "sg:person.0725454752.99", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0725454752.99"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr 31, 119991, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/grid.435216.7", 
          "name": [
            "Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr 31, 119991, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Sergienko", 
        "givenName": "V. S.", 
        "id": "sg:person.0656275315.49", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0656275315.49"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1007/3-540-15811-1_3", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1006398862", 
          "https://doi.org/10.1007/3-540-15811-1_3"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2006-10", 
    "datePublishedReg": "2006-10-01", 
    "description": "Complex (p-O2NC6H4NH3)2SiF6 (I) is prepared by reacting fluorostlicic acid with p-nitroaniline in methanol and structurally studied using single-crystal X-ray diffraction. In the ionic structure of this complex, SiF62\u2212 centrosymmetrical anions (avg. Si-F, 1.671(3) \u00c5) and O2NC6H4NH3+ cations are linked through NH\u2026F interionic H-bonds (N\u2026F 2.823(5)-3.205(7) \u00c5). The thermochemical features of complex I are discussed in light of the structure data.", 
    "genre": "article", 
    "id": "sg:pub.10.1134/s0036023606100081", 
    "inLanguage": "en", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1004031", 
        "issn": [
          "0036-0236", 
          "0044-457X"
        ], 
        "name": "Russian Journal of Inorganic Chemistry", 
        "publisher": "Pleiades Publishing", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "10", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "51"
      }
    ], 
    "keywords": [
      "ionic structure", 
      "centrosymmetrical anions", 
      "ray diffraction", 
      "thermochemical features", 
      "crystal structure", 
      "structure data", 
      "anions", 
      "hexafluorosilicate", 
      "cations", 
      "nitroaniline", 
      "diffraction", 
      "bonds", 
      "methanol", 
      "structure", 
      "NH", 
      "complexes", 
      "complex I", 
      "acid", 
      "light", 
      "features", 
      "data", 
      "fluorostlicic acid", 
      "O2NC6H4NH3", 
      "nitroanilinium hexafluorosilicate"
    ], 
    "name": "Crystal structure of p-nitroanilinium hexafluorosilicate", 
    "pagination": "1561-1564", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1031948780"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1134/s0036023606100081"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1134/s0036023606100081", 
      "https://app.dimensions.ai/details/publication/pub.1031948780"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2021-11-01T18:09", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20211101/entities/gbq_results/article/article_426.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1134/s0036023606100081"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s0036023606100081'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s0036023606100081'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s0036023606100081'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s0036023606100081'


 

This table displays all metadata directly associated to this object as RDF triples.

113 TRIPLES      22 PREDICATES      51 URIs      42 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1134/s0036023606100081 schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author N3712d61b254043b1a544e8dd16e31f3e
4 schema:citation sg:pub.10.1007/3-540-15811-1_3
5 schema:datePublished 2006-10
6 schema:datePublishedReg 2006-10-01
7 schema:description Complex (p-O2NC6H4NH3)2SiF6 (I) is prepared by reacting fluorostlicic acid with p-nitroaniline in methanol and structurally studied using single-crystal X-ray diffraction. In the ionic structure of this complex, SiF62− centrosymmetrical anions (avg. Si-F, 1.671(3) Å) and O2NC6H4NH3+ cations are linked through NH…F interionic H-bonds (N…F 2.823(5)-3.205(7) Å). The thermochemical features of complex I are discussed in light of the structure data.
8 schema:genre article
9 schema:inLanguage en
10 schema:isAccessibleForFree false
11 schema:isPartOf Nb54388f30a8c4c4ab51abf71da17d22d
12 Nedccde459e3d4b0aaccfaf75dc819fb6
13 sg:journal.1004031
14 schema:keywords NH
15 O2NC6H4NH3
16 acid
17 anions
18 bonds
19 cations
20 centrosymmetrical anions
21 complex I
22 complexes
23 crystal structure
24 data
25 diffraction
26 features
27 fluorostlicic acid
28 hexafluorosilicate
29 ionic structure
30 light
31 methanol
32 nitroaniline
33 nitroanilinium hexafluorosilicate
34 ray diffraction
35 structure
36 structure data
37 thermochemical features
38 schema:name Crystal structure of p-nitroanilinium hexafluorosilicate
39 schema:pagination 1561-1564
40 schema:productId Ncfe6caf349a341d7aa3d7022b445dc41
41 Nd8dc5f78cb8f414fbee2a23e9d219fc4
42 schema:sameAs https://app.dimensions.ai/details/publication/pub.1031948780
43 https://doi.org/10.1134/s0036023606100081
44 schema:sdDatePublished 2021-11-01T18:09
45 schema:sdLicense https://scigraph.springernature.com/explorer/license/
46 schema:sdPublisher N638e33812d384ed88c9602aefc88f994
47 schema:url https://doi.org/10.1134/s0036023606100081
48 sgo:license sg:explorer/license/
49 sgo:sdDataset articles
50 rdf:type schema:ScholarlyArticle
51 N1c5e443f367f4699bfd5916004be181a rdf:first sg:person.0725454752.99
52 rdf:rest Nca3f99b5fc144a2ea3b493973e7046ba
53 N3712d61b254043b1a544e8dd16e31f3e rdf:first sg:person.013621052757.70
54 rdf:rest Nedeff7ab45ec4ca9bee330af0007c113
55 N638e33812d384ed88c9602aefc88f994 schema:name Springer Nature - SN SciGraph project
56 rdf:type schema:Organization
57 Nb54388f30a8c4c4ab51abf71da17d22d schema:volumeNumber 51
58 rdf:type schema:PublicationVolume
59 Nca3f99b5fc144a2ea3b493973e7046ba rdf:first sg:person.0656275315.49
60 rdf:rest rdf:nil
61 Ncfe6caf349a341d7aa3d7022b445dc41 schema:name doi
62 schema:value 10.1134/s0036023606100081
63 rdf:type schema:PropertyValue
64 Nd8dc5f78cb8f414fbee2a23e9d219fc4 schema:name dimensions_id
65 schema:value pub.1031948780
66 rdf:type schema:PropertyValue
67 Nedccde459e3d4b0aaccfaf75dc819fb6 schema:issueNumber 10
68 rdf:type schema:PublicationIssue
69 Nedeff7ab45ec4ca9bee330af0007c113 rdf:first sg:person.016003603003.53
70 rdf:rest N1c5e443f367f4699bfd5916004be181a
71 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
72 schema:name Chemical Sciences
73 rdf:type schema:DefinedTerm
74 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
75 schema:name Physical Chemistry (incl. Structural)
76 rdf:type schema:DefinedTerm
77 sg:journal.1004031 schema:issn 0036-0236
78 0044-457X
79 schema:name Russian Journal of Inorganic Chemistry
80 schema:publisher Pleiades Publishing
81 rdf:type schema:Periodical
82 sg:person.013621052757.70 schema:affiliation grid-institutes:grid.418751.e
83 schema:familyName Gel’mbol’dt
84 schema:givenName V. O.
85 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013621052757.70
86 rdf:type schema:Person
87 sg:person.016003603003.53 schema:affiliation grid-institutes:grid.435216.7
88 schema:familyName Minacheva
89 schema:givenName L. Kh.
90 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016003603003.53
91 rdf:type schema:Person
92 sg:person.0656275315.49 schema:affiliation grid-institutes:grid.435216.7
93 schema:familyName Sergienko
94 schema:givenName V. S.
95 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0656275315.49
96 rdf:type schema:Person
97 sg:person.0725454752.99 schema:affiliation grid-institutes:None
98 schema:familyName Ganin
99 schema:givenName E. V.
100 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0725454752.99
101 rdf:type schema:Person
102 sg:pub.10.1007/3-540-15811-1_3 schema:sameAs https://app.dimensions.ai/details/publication/pub.1006398862
103 https://doi.org/10.1007/3-540-15811-1_3
104 rdf:type schema:CreativeWork
105 grid-institutes:None schema:alternateName Odessa State Ecological University, Lvovskaya ul., 15, 65016, Odessa, Ukraine
106 schema:name Odessa State Ecological University, Lvovskaya ul., 15, 65016, Odessa, Ukraine
107 rdf:type schema:Organization
108 grid-institutes:grid.418751.e schema:alternateName Physicochemical Institute of Environmental and Human Protection, Ministry of Education and Science of Ukraine and National Academy of Sciences of Ukraine, Preobrazhenskaya ul. 3, 65082, Odessa, Ukraine
109 schema:name Physicochemical Institute of Environmental and Human Protection, Ministry of Education and Science of Ukraine and National Academy of Sciences of Ukraine, Preobrazhenskaya ul. 3, 65082, Odessa, Ukraine
110 rdf:type schema:Organization
111 grid-institutes:grid.435216.7 schema:alternateName Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr 31, 119991, Moscow, Russia
112 schema:name Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr 31, 119991, Moscow, Russia
113 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...