Synthesis and crystal structure of the copper(II) valerate complex with nicotinamide View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2006-06

AUTHORS

A. S. Antsyshkina, T. V. Koksharova, G. G. Sadikov, I. S. Gritsenko, V. S. Sergienko, O. A. Egorova

ABSTRACT

A coordination compound of copper(II) valerate with nicotinamide, [CuL(C4H9COO)2]2 (I), has been synthesized, and its crystal structure has been determined by X-ray crystallography. The crystals of I are triclinic: a = 9.1245(9) Å, b = 9.8572(6) Å, c = 11.0944(9) Å, α = 73.51(1)°, β = 79.917(6)°, γ = 72.161(7)°, Z = 2, space group . In the centrosymmetric binuclear molecule of I, the copper atoms (Cu...Cu′, 2.621 Å) are linked through four bidentate chelating valerate ligands (av., Cu-O 1.969 Å). The coordination polyhedron of the Cu atom is a tetragonal pyramid with the nitrogen atom of the pyridine ring in the apical position at a longer distance (Cu-N, 2.190 Å). More... »

PAGES

901-907

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s003602360606009x

DOI

http://dx.doi.org/10.1134/s003602360606009x

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1050557433


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0302", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Inorganic Chemistry", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, 119991, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Antsyshkina", 
        "givenName": "A. S.", 
        "id": "sg:person.015007226477.01", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015007226477.01"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "name": [
            "Mechnikov University, ul. Dvoryanskaya 2, 65026, Odessa, Ukraine"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Koksharova", 
        "givenName": "T. V.", 
        "id": "sg:person.016311020231.06", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016311020231.06"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, 119991, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Sadikov", 
        "givenName": "G. G.", 
        "id": "sg:person.016005276117.42", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016005276117.42"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "name": [
            "Mechnikov University, ul. Dvoryanskaya 2, 65026, Odessa, Ukraine"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Gritsenko", 
        "givenName": "I. S.", 
        "id": "sg:person.016451076665.37", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016451076665.37"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, 119991, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Sergienko", 
        "givenName": "V. S.", 
        "id": "sg:person.0656275315.49", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0656275315.49"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Peoples' Friendship University of Russia", 
          "id": "https://www.grid.ac/institutes/grid.77642.30", 
          "name": [
            "Peoples\u2019 Friendship University, ul. Miklukho-Maklaya 6, 177198, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Egorova", 
        "givenName": "O. A.", 
        "id": "sg:person.012742363356.44", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012742363356.44"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1107/s0108767390000277", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1010133616"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0040-6031(01)00758-4", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1038293374"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2006-06", 
    "datePublishedReg": "2006-06-01", 
    "description": "A coordination compound of copper(II) valerate with nicotinamide, [CuL(C4H9COO)2]2 (I), has been synthesized, and its crystal structure has been determined by X-ray crystallography. The crystals of I are triclinic: a = 9.1245(9) \u00c5, b = 9.8572(6) \u00c5, c = 11.0944(9) \u00c5, \u03b1 = 73.51(1)\u00b0, \u03b2 = 79.917(6)\u00b0, \u03b3 = 72.161(7)\u00b0, Z = 2, space group . In the centrosymmetric binuclear molecule of I, the copper atoms (Cu...Cu\u2032, 2.621 \u00c5) are linked through four bidentate chelating valerate ligands (av., Cu-O 1.969 \u00c5). The coordination polyhedron of the Cu atom is a tetragonal pyramid with the nitrogen atom of the pyridine ring in the apical position at a longer distance (Cu-N, 2.190 \u00c5).", 
    "genre": "research_article", 
    "id": "sg:pub.10.1134/s003602360606009x", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1004031", 
        "issn": [
          "0036-0236", 
          "0044-457X"
        ], 
        "name": "Russian Journal of Inorganic Chemistry", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "6", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "51"
      }
    ], 
    "name": "Synthesis and crystal structure of the copper(II) valerate complex with nicotinamide", 
    "pagination": "901-907", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "f0d7205c09248764f7fd84a622887d7973e33eb516be6cd6e65f73a00b8608b4"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1134/s003602360606009x"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1050557433"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1134/s003602360606009x", 
      "https://app.dimensions.ai/details/publication/pub.1050557433"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-10T17:30", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8672_00000508.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1134/S003602360606009X"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s003602360606009x'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s003602360606009x'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s003602360606009x'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s003602360606009x'


 

This table displays all metadata directly associated to this object as RDF triples.

109 TRIPLES      21 PREDICATES      29 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1134/s003602360606009x schema:about anzsrc-for:03
2 anzsrc-for:0302
3 schema:author N43f4df5af8a44698a6d1af5958e259d5
4 schema:citation https://doi.org/10.1016/s0040-6031(01)00758-4
5 https://doi.org/10.1107/s0108767390000277
6 schema:datePublished 2006-06
7 schema:datePublishedReg 2006-06-01
8 schema:description A coordination compound of copper(II) valerate with nicotinamide, [CuL(C4H9COO)2]2 (I), has been synthesized, and its crystal structure has been determined by X-ray crystallography. The crystals of I are triclinic: a = 9.1245(9) Å, b = 9.8572(6) Å, c = 11.0944(9) Å, α = 73.51(1)°, β = 79.917(6)°, γ = 72.161(7)°, Z = 2, space group . In the centrosymmetric binuclear molecule of I, the copper atoms (Cu...Cu′, 2.621 Å) are linked through four bidentate chelating valerate ligands (av., Cu-O 1.969 Å). The coordination polyhedron of the Cu atom is a tetragonal pyramid with the nitrogen atom of the pyridine ring in the apical position at a longer distance (Cu-N, 2.190 Å).
9 schema:genre research_article
10 schema:inLanguage en
11 schema:isAccessibleForFree false
12 schema:isPartOf N153ee7e3162e46159896e1412632983c
13 N94477ad97eec41d08a6029194448705e
14 sg:journal.1004031
15 schema:name Synthesis and crystal structure of the copper(II) valerate complex with nicotinamide
16 schema:pagination 901-907
17 schema:productId N0eb14f92e0634febb84993f1440446ad
18 Nc4e6b6bb0e0a44cb9b049a5209abb8d8
19 Nf340e9575b5e459bb59f79fa3c39d7e0
20 schema:sameAs https://app.dimensions.ai/details/publication/pub.1050557433
21 https://doi.org/10.1134/s003602360606009x
22 schema:sdDatePublished 2019-04-10T17:30
23 schema:sdLicense https://scigraph.springernature.com/explorer/license/
24 schema:sdPublisher N9410d6bba5b6415bbf784600b3802a58
25 schema:url http://link.springer.com/10.1134/S003602360606009X
26 sgo:license sg:explorer/license/
27 sgo:sdDataset articles
28 rdf:type schema:ScholarlyArticle
29 N0eae6f8c87be4916a4613812de77674c rdf:first sg:person.012742363356.44
30 rdf:rest rdf:nil
31 N0eb14f92e0634febb84993f1440446ad schema:name readcube_id
32 schema:value f0d7205c09248764f7fd84a622887d7973e33eb516be6cd6e65f73a00b8608b4
33 rdf:type schema:PropertyValue
34 N153ee7e3162e46159896e1412632983c schema:volumeNumber 51
35 rdf:type schema:PublicationVolume
36 N26f742f3d3ec4b3095e410ef7fbf0e50 rdf:first sg:person.016451076665.37
37 rdf:rest N40679eb952034897b2a30030b5448fbf
38 N40679eb952034897b2a30030b5448fbf rdf:first sg:person.0656275315.49
39 rdf:rest N0eae6f8c87be4916a4613812de77674c
40 N43f4df5af8a44698a6d1af5958e259d5 rdf:first sg:person.015007226477.01
41 rdf:rest Na08c7bf26e80474daea2bc8b2d30477a
42 N90407fffe5cb43488de7d6cf42620d64 schema:name Mechnikov University, ul. Dvoryanskaya 2, 65026, Odessa, Ukraine
43 rdf:type schema:Organization
44 N9410d6bba5b6415bbf784600b3802a58 schema:name Springer Nature - SN SciGraph project
45 rdf:type schema:Organization
46 N94477ad97eec41d08a6029194448705e schema:issueNumber 6
47 rdf:type schema:PublicationIssue
48 Na08c7bf26e80474daea2bc8b2d30477a rdf:first sg:person.016311020231.06
49 rdf:rest Nbb84063bcd1c490da28791c60445385e
50 Nbb84063bcd1c490da28791c60445385e rdf:first sg:person.016005276117.42
51 rdf:rest N26f742f3d3ec4b3095e410ef7fbf0e50
52 Nc4e6b6bb0e0a44cb9b049a5209abb8d8 schema:name doi
53 schema:value 10.1134/s003602360606009x
54 rdf:type schema:PropertyValue
55 Nf340e9575b5e459bb59f79fa3c39d7e0 schema:name dimensions_id
56 schema:value pub.1050557433
57 rdf:type schema:PropertyValue
58 Nf383611be5fa4af1a5fd6428e7c04418 schema:name Mechnikov University, ul. Dvoryanskaya 2, 65026, Odessa, Ukraine
59 rdf:type schema:Organization
60 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
61 schema:name Chemical Sciences
62 rdf:type schema:DefinedTerm
63 anzsrc-for:0302 schema:inDefinedTermSet anzsrc-for:
64 schema:name Inorganic Chemistry
65 rdf:type schema:DefinedTerm
66 sg:journal.1004031 schema:issn 0036-0236
67 0044-457X
68 schema:name Russian Journal of Inorganic Chemistry
69 rdf:type schema:Periodical
70 sg:person.012742363356.44 schema:affiliation https://www.grid.ac/institutes/grid.77642.30
71 schema:familyName Egorova
72 schema:givenName O. A.
73 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012742363356.44
74 rdf:type schema:Person
75 sg:person.015007226477.01 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
76 schema:familyName Antsyshkina
77 schema:givenName A. S.
78 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015007226477.01
79 rdf:type schema:Person
80 sg:person.016005276117.42 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
81 schema:familyName Sadikov
82 schema:givenName G. G.
83 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016005276117.42
84 rdf:type schema:Person
85 sg:person.016311020231.06 schema:affiliation N90407fffe5cb43488de7d6cf42620d64
86 schema:familyName Koksharova
87 schema:givenName T. V.
88 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016311020231.06
89 rdf:type schema:Person
90 sg:person.016451076665.37 schema:affiliation Nf383611be5fa4af1a5fd6428e7c04418
91 schema:familyName Gritsenko
92 schema:givenName I. S.
93 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016451076665.37
94 rdf:type schema:Person
95 sg:person.0656275315.49 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
96 schema:familyName Sergienko
97 schema:givenName V. S.
98 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0656275315.49
99 rdf:type schema:Person
100 https://doi.org/10.1016/s0040-6031(01)00758-4 schema:sameAs https://app.dimensions.ai/details/publication/pub.1038293374
101 rdf:type schema:CreativeWork
102 https://doi.org/10.1107/s0108767390000277 schema:sameAs https://app.dimensions.ai/details/publication/pub.1010133616
103 rdf:type schema:CreativeWork
104 https://www.grid.ac/institutes/grid.4886.2 schema:alternateName Russian Academy of Sciences
105 schema:name Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, 119991, Moscow, Russia
106 rdf:type schema:Organization
107 https://www.grid.ac/institutes/grid.77642.30 schema:alternateName Peoples' Friendship University of Russia
108 schema:name Peoples’ Friendship University, ul. Miklukho-Maklaya 6, 177198, Moscow, Russia
109 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...