Synthesis and crystal structure of the copper(II) valerate complex with nicotinamide View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2006-06

AUTHORS

A. S. Antsyshkina, T. V. Koksharova, G. G. Sadikov, I. S. Gritsenko, V. S. Sergienko, O. A. Egorova

ABSTRACT

A coordination compound of copper(II) valerate with nicotinamide, [CuL(C4H9COO)2]2 (I), has been synthesized, and its crystal structure has been determined by X-ray crystallography. The crystals of I are triclinic: a = 9.1245(9) Å, b = 9.8572(6) Å, c = 11.0944(9) Å, α = 73.51(1)°, β = 79.917(6)°, γ = 72.161(7)°, Z = 2, space group . In the centrosymmetric binuclear molecule of I, the copper atoms (Cu...Cu′, 2.621 Å) are linked through four bidentate chelating valerate ligands (av., Cu-O 1.969 Å). The coordination polyhedron of the Cu atom is a tetragonal pyramid with the nitrogen atom of the pyridine ring in the apical position at a longer distance (Cu-N, 2.190 Å). More... »

PAGES

901-907

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s003602360606009x

DOI

http://dx.doi.org/10.1134/s003602360606009x

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1050557433


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