Synthesis and crystal structure of diaquadibenzoatobis(nicotinamide)nickel(II) View Full Text


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Article Info

DATE

2006-06

AUTHORS

T. V. Koksharova, G. G. Sadikov, A. S. Antsyshkina, I. S. Gritsenko, V. S. Sergienko, O. A. Egorova

ABSTRACT

A coordination compound of nickel(II) benzoate with nicotinamide [Ni(C6H5COO)2(L)2(H2O)2] (I) (L is nicotinic acid amide) is synthesized and studied by IR spectroscopy. Its crystal structure is solved by X-ray crystallography. The crystals of compound I are monoclinic: a = 7.152 Å, b = 18.266 Å, c = 10.341 Å, β = 109.24°, V = 1275.4 Å3, Z = 2, space group P21/c. Structural units of a crystal of I are centrosymmetric octahedral complex molecules. The coordination environment of the Ni atom contains two O atoms (Ni-O(1) 2.066(2) Å) and two N atoms (Ni-N(1) 2.091(2) Å) of the monodentate-coordinated benzoate anions and nicotinamide molecules, respectively, as well as two O atoms of the H2O molecules (Ni-O(1w) 2.110(2) Å). More... »

PAGES

895-900

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0036023606060088

DOI

http://dx.doi.org/10.1134/s0036023606060088

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1036123330


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