Synthesis and crystal structure of tris(ɛ-caprolactamium) hexa(isothiocyanato)chromate(III) tricaprolactam (C6H14NO)3[Cr(NCS)6] · 3(C6H13NO) View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2006-04

AUTHORS

E. V. Cherkasova, A. V. Virovets, E. V. Peresypkina, T. G. Cherkasova, E. S. Tatarinova

ABSTRACT

A novel complex, tris(ɛ-caprolactamium) hexa(isothiocyanato)chromate(III) tricaprolactam (C6H12NO)3[Cr(NCS)6] · 3(C6H11NO), has been synthesized and characterized by X-ray diffraction. The structure can be referred to the discrete ionic type. The coordination polyhedron of the chromium atom is a nearly regular octahedron. The crystals of the complex (C42H69CrN12O6S6, FW = 1082.45) are triclinic, space group P, Z = 1, V = 1359.3(2) Å3, dcalcd = 1.322 g/cm3. Unit cell parameters: a = 11.1784(9) Å, b = 11.3196(7) Å, c = 12.580(2) Å, α = 109.347(5)°, β = 106.304(5)°, γ = 102.025(4)°. The unit cell contains three caprolactamium cations and three caprolactam molecules related by the inversion center of the space group, which leads to random occupancy of the positions of the cations and solvation molecules. More... »

PAGES

557-562

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0036023606040085

DOI

http://dx.doi.org/10.1134/s0036023606040085

DIMENSIONS

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