Crystal structure of Na6[(UO2)3O(OH)3(SeO4)2]2 · 10H2O View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2006-02

AUTHORS

E. E. Baeva, A. V. Virovets, E. V. Peresypkina, L. B. Serezhkina

ABSTRACT

The complex Na6[(UO2)3O(OH)3(SeO4)2]2 · 10H2O (I) is synthesized and studied by X-ray diffraction. The compound crystallizes in the orthorhombic crystal system with the unit cell parameters: a = 14.2225(7) Å, b = 18.3601(7) Å, c = 16.5406(6) Å, V = 4319.2(3) Å3, Z = 4, space group Cmcm, R1 = 0.0406. Compound I is found to be a representative of the crystal-chemical group A3M3M23T32 (A = UO2+2, M3 = O2−, M2 = OH−, T3 = SeO2−4) of the uranyl complexes; it contains layer uranium-containing groups [(UO2)3O(OH)3(SeO4)2]3−. These layers linked to form a three-dimensional cage through bonds formed by the sodium atoms with the oxygen atoms of the uranyl ions and SeO4 groups that belong to different layers. More... »

PAGES

220-228

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0036023606020094

DOI

http://dx.doi.org/10.1134/s0036023606020094

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1047833311


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