Ontology type: schema:ScholarlyArticle
2006-02
AUTHORSV. O. Gel’mbol’dt, E. V. Ganin, L. V. Koroeva, L. Kh. Minacheva, V. S. Sergienko, A. A. Ennan
ABSTRACTThe reaction of 45% fluorosilicic acid with methanol solutions of several 2-substituted anilines(L) gave hexafluorosilicates (LH)2SiF6. The products were studied by elemental analysis, IR spectroscopy, mass spectrometry, and thermogravimetry. The solubility and the hydrolytic stability of the salts were estimated. The structure of the complex [CH3O(O)CC6H4NH3]2SiF6 was determined by single-crystal X-ray diffraction. The ionic structure is composed of centrosymmetric SiF62− anions (the average Si-F bond length is 1.679(1) Å) and the [CH3O(O)CC6H4NH3]+ cations. The NH3+ group is the donor for the inner-cation H-bond with the carbonyl oxygen atom (NH···O), and for two ion-ion H-bonds (NH···F). The Si-F bond lengths correlate with the strengths of the H-bonds involving the corresponding fluorine atoms. More... »
PAGES194-201
http://scigraph.springernature.com/pub.10.1134/s0036023606020069
DOIhttp://dx.doi.org/10.1134/s0036023606020069
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