Hexafluorosilicates of 2-substituted anilinium derivatives View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2006-02

AUTHORS

V. O. Gel’mbol’dt, E. V. Ganin, L. V. Koroeva, L. Kh. Minacheva, V. S. Sergienko, A. A. Ennan

ABSTRACT

The reaction of 45% fluorosilicic acid with methanol solutions of several 2-substituted anilines(L) gave hexafluorosilicates (LH)2SiF6. The products were studied by elemental analysis, IR spectroscopy, mass spectrometry, and thermogravimetry. The solubility and the hydrolytic stability of the salts were estimated. The structure of the complex [CH3O(O)CC6H4NH3]2SiF6 was determined by single-crystal X-ray diffraction. The ionic structure is composed of centrosymmetric SiF62− anions (the average Si-F bond length is 1.679(1) Å) and the [CH3O(O)CC6H4NH3]+ cations. The NH3+ group is the donor for the inner-cation H-bond with the carbonyl oxygen atom (NH···O), and for two ion-ion H-bonds (NH···F). The Si-F bond lengths correlate with the strengths of the H-bonds involving the corresponding fluorine atoms. More... »

PAGES

194-201

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0036023606020069

DOI

http://dx.doi.org/10.1134/s0036023606020069

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1051511302


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