Mechanochemical Formation of Solid Solution of Aluminum in Copper View Full Text


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Article Info

DATE

2021-04

AUTHORS

T. F. Grigoreva, S. A. Petrova, S. A. Kovaleva, T. Yu. Kiseleva, S. I. Zholudev, S. V. Vosmerikov, T. A. Udalova, E. T. Devyatkina, S. N. Polyakov, N. Z. Lyakhov

ABSTRACT

X-ray diffraction analysis is used to study the mechanochemical formation of a solid solution in the Cu–10 wt % Al system. The formation of the solid solution is shown to occur via the formation of the CuAl2 and Cu9Al4 intermetallic compounds, which, in the course of mechanical activation, react with residual copper to form the Cu(Al), solid solution of aluminum in copper. Under the conditions of mechanical activation in a high-energy planetary ball mill, the two-phase product of the mechanochemical synthesis, namely, 90 wt % Cu(Al) + 10 wt % Cu9Al4 forms is formed. It is shown that the maximum reached Al concentration in the solid solution is 7.4 wt %. The microstresses of the solid solution are ~1%; the crystallite size reaches 35–40 nm. More... »

PAGES

370-375

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0031918x21030066

DOI

http://dx.doi.org/10.1134/s0031918x21030066

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1138789904


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175 grid-institutes:grid.464702.3 schema:alternateName Technological Institute for Superhard and Novel Carbon Materials, 108840, Troitsk, Russia
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181 grid-institutes:grid.494915.4 schema:alternateName Joint Institute of Mechanical Engineering, National Academy of Sciences of Belarus, 220072, Minsk, Republic of Belarus
182 schema:name Joint Institute of Mechanical Engineering, National Academy of Sciences of Belarus, 220072, Minsk, Republic of Belarus
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184 grid-institutes:grid.77667.37 schema:alternateName Novosibirsk State Technical University, 630073, Novosibirsk, Russia
185 schema:name Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch, Russian Academy of Sciences, 630128, Novosibirsk, Russia
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