Mechanical and magnetic properties of alloys near the concentration range of the existence of Co3(Al,W) intermetallic compound View Full Text


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Article Info

DATE

2017-05

AUTHORS

N. V. Kazantseva, D. I. Davydov, P. B. Terent’ev, D. A. Shishkin, S. L. Demakov, A. S. Yurovskikh, E. P. Romanov

ABSTRACT

An experimental study of the mechanical and magnetic properties of Co–8 at % Al–X at % W (where Х = 4.6; 6.8; 8.5; 10; 12) polycrystalline alloys has been carried out depending on the tungsten content. It has been shown that an increase in the tungsten content induces the following changes: Young’s modulus changes from 240 to 259 GPa and the microhardness HV changes from 290 to 413 MPa. The Curie temperature of the intermetallic γ' phase (L12) grows from 1025 to 1049 K, and the saturation magnetization of the alloys decreases. The value of the coercive force also increases, from 1 to 500 Oe. The calculations of the specific heat of the γ' (L12)–γ (dcc) phase transition has shown that the highest amount of heat (304 J/g) is absorbed upon the phase transition in the sample containing the largest amount of tungsten (12.6 at %). The results obtained indicate the diffusion character of the transition, the rate of which is controlled by the diffusion of the slowest component of the alloy (in this case, tungsten). It has been found that the solvus temperature of the γ' phase increases from 1009 to 1044°С with an increase in the tungsten content from 4.6 to 12.6 at %. More... »

PAGES

432-438

References to SciGraph publications

  • 2014-08-14. Spinodal Decomposition Mechanism of γ′ Precipitation in a Single Crystal Ni-Based Superalloy in METALLURGICAL AND MATERIALS TRANSACTIONS A
  • 1989-12. The Al-Co (Aluminum-Cobalt) system in JOURNAL OF PHASE EQUILIBRIA AND DIFFUSION
  • 2008-05-27. Velocities of elastic waves and the elasticity moduli of nickel-base superalloys and of the 60N21 alloy in PHYSICS OF METALS AND METALLOGRAPHY
  • 2015-06-17. Study of magnetic properties and structural and phase transformations in the Co-19 at % Al-6 at % W alloy in PHYSICS OF METALS AND METALLOGRAPHY
  • 2007-11-10. Co-W (Cobalt-Tungsten) in JOURNAL OF PHASE EQUILIBRIA AND DIFFUSION
  • 2016-07-23. Phase diagram of the Co–Al–W system. structure and phase transformations near the Co3(Al, W) intermetallic composition range in PHYSICS OF METALS AND METALLOGRAPHY
  • 2016-01. Study of the martensitic transformation in the Co–9 at % Al alloy in PHYSICS OF METALS AND METALLOGRAPHY
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    http://scigraph.springernature.com/pub.10.1134/s0031918x17050064

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    http://dx.doi.org/10.1134/s0031918x17050064

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