Optical Spectra of Gamma-Irradiated LiF Crystals with Anisotropic Lithium Nanoparticles View Full Text


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Article Info

DATE

2018-05

AUTHORS

M. A. Mussaeva, E. M. Ibragimova, Sh. N. Buzrikov

ABSTRACT

The optical response of Li anisotropic defects and nanoparticles from three faces of cubic LiF crystals with 10-mm edges to γ radiation from a 60Со source with doses of 105–109 R at 320 K in air is studied. After a maximum dose of 109 R, scanning electron microscopy revealed submicron metal lithium flakes ordered into long parallel nanofilaments. The resonance absorption band, which shifts from 272 to 295 nm with increasing dose, is assigned to lithium nanocolloids in the (110) plane. The band at 202–225 nm observed only from the (100) face narrows at doses below 105 R and is assigned to diatomic fluorine molecules in interstitial sites. The appearance of the 209–212–215-nm triplets at 2.7 × 105 R from the (100) plane and the 211–213–215-nm triplets at 0.9 × 105 R from the (010) plane is related to radiation-induced axially symmetric bipolarons with a high oscillator strength. The splitting of the 445-nm band into a 438–445–450-nm triplet is observed only for the (010) plane after a dose of 106 R and is related to surface plasmon polaritons (longitudinal and transverse) of elongated Li nanoparticles. The (F2–F3) complexes are oriented in the most imperfect (111) plane and are seen along three cubic axes. More... »

PAGES

644-648

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0030400x18050144

DOI

http://dx.doi.org/10.1134/s0030400x18050144

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1105208725


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