Excitonic nature of the dual fluorescence of 2,3-diazabicyclo[2.2.2]oct-2-ene and 1,4-dimethyl-(2,3-diazabicyclo[2.2.2]oct-2-ene) View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2014-10

AUTHORS

V. A. Povedailo, D. L. Yakovlev

ABSTRACT

Absorption, fluorescence excitation, and fluorescence spectra and the dependence of the degree of fluorescence polarization on the emission wavelength are measured for glass-like ethanol solutions of 2,3-diazabicyclo[2.2.2]oct-2-ene and 1,4-dimethyl-(2,3-diazabicyclo[2.2.2]oct-2-ene) at a temperature of 77 K. The analysis of the spectral polarization data shows that two excited electronic states S1 and S2 that contribute to the emission of the compounds are related to the exciton splitting and correspond to the symmetric (S2) and antisymmetric (S1) wave functions. More... »

PAGES

534-539

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0030400x1410018x

DOI

http://dx.doi.org/10.1134/s0030400x1410018x

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1039696025


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