Particular features of fluorescence of jet-cooled vapor of 2,3-diazabicyclooctene View Full Text


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Article Info

DATE

2013-03

AUTHORS

A. P. Lugovskii, V. A. Povedailo, V. A. Tolkachev, D. L. Yakovlev

ABSTRACT

The fluorescence and fluorescence excitation spectra of azocompound, 2,3-diazabicyclo[2.2.2]oct-2-ene, have been studied using jet cooling. The violation of the mirror symmetry between the fluorescence and fluorescence excitation spectra due to an intense long-wavelength emission that manifests itself in solutions and in the gas phase cannot be eliminated even by jet cooling. It has been revealed that the bands of pure electronic and vibronic transitions are split by 0.55 cm−1, which is caused by tunneling with accompanying emission from an intermediate short-lived state and which may be the reason for the violation of the mirror symmetry of the spectra upon tunnel inversion. More... »

PAGES

353-358

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0030400x13030181

DOI

http://dx.doi.org/10.1134/s0030400x13030181

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1051630516


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