Photophysics of the analogs of pyrromethene PM 567 View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2012-09-15

AUTHORS

A. N. Sinel’nikov, V. Ya. Artyukhov, Yu. V. Aksenova, R. T. Kuznetsova

ABSTRACT

The spectral and luminescence properties of a number of pyrromethene (PM) dyes have been investigated. The absorption and luminescence spectra of PM molecules in different solvents are measured. The electronic structure and electronic excited states are calculated by the method of intermediate neglect of differential overlap with special spectroscopic parameterization. The rate constants of photophysical processes are estimated, and the fluorescence quantum yields are calculated. The fluorescence quantum yields of PM I and PM II molecules are found to decrease upon their excitation to the second short-wavelength absorption band. This phenomenon is interpreted. More... »

PAGES

291-297

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0030400x12070223

DOI

http://dx.doi.org/10.1134/s0030400x12070223

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1017014354


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/02", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0205", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Optical Physics", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Tomsk State University, 634050, Tomsk, Russia", 
          "id": "http://www.grid.ac/institutes/grid.77602.34", 
          "name": [
            "Tomsk State University, 634050, Tomsk, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Sinel\u2019nikov", 
        "givenName": "A. N.", 
        "id": "sg:person.010102045670.36", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010102045670.36"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Tomsk State University, 634050, Tomsk, Russia", 
          "id": "http://www.grid.ac/institutes/grid.77602.34", 
          "name": [
            "Tomsk State University, 634050, Tomsk, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Artyukhov", 
        "givenName": "V. Ya.", 
        "id": "sg:person.012340244103.07", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012340244103.07"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Tomsk State University, 634050, Tomsk, Russia", 
          "id": "http://www.grid.ac/institutes/grid.77602.34", 
          "name": [
            "Tomsk State University, 634050, Tomsk, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Aksenova", 
        "givenName": "Yu. V.", 
        "id": "sg:person.010042754475.67", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010042754475.67"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Tomsk State University, 634050, Tomsk, Russia", 
          "id": "http://www.grid.ac/institutes/grid.77602.34", 
          "name": [
            "Tomsk State University, 634050, Tomsk, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Kuznetsova", 
        "givenName": "R. T.", 
        "id": "sg:person.01212220113.37", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01212220113.37"
        ], 
        "type": "Person"
      }
    ], 
    "datePublished": "2012-09-15", 
    "datePublishedReg": "2012-09-15", 
    "description": "The spectral and luminescence properties of a number of pyrromethene (PM) dyes have been investigated. The absorption and luminescence spectra of PM molecules in different solvents are measured. The electronic structure and electronic excited states are calculated by the method of intermediate neglect of differential overlap with special spectroscopic parameterization. The rate constants of photophysical processes are estimated, and the fluorescence quantum yields are calculated. The fluorescence quantum yields of PM I and PM II molecules are found to decrease upon their excitation to the second short-wavelength absorption band. This phenomenon is interpreted.", 
    "genre": "article", 
    "id": "sg:pub.10.1134/s0030400x12070223", 
    "inLanguage": "en", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1294762", 
        "issn": [
          "0030-400X", 
          "1562-6911"
        ], 
        "name": "Optics and Spectroscopy", 
        "publisher": "Pleiades Publishing", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "3", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "113"
      }
    ], 
    "keywords": [
      "fluorescence quantum yield", 
      "quantum yield", 
      "short-wavelength absorption band", 
      "electronic excited states", 
      "spectroscopic parameterization", 
      "pyrromethene dyes", 
      "luminescence properties", 
      "photophysical processes", 
      "different solvents", 
      "intermediate neglect", 
      "PM molecules", 
      "electronic structure", 
      "absorption bands", 
      "luminescence spectra", 
      "differential overlap", 
      "rate constants", 
      "excited states", 
      "molecules", 
      "solvent", 
      "photophysics", 
      "yield", 
      "dye", 
      "spectra", 
      "constants", 
      "PM I", 
      "absorption", 
      "properties", 
      "structure", 
      "analogues", 
      "band", 
      "excitation", 
      "process", 
      "method", 
      "state", 
      "phenomenon", 
      "overlap", 
      "parameterization", 
      "number", 
      "neglect", 
      "special spectroscopic parameterization", 
      "PM II molecules", 
      "II molecules", 
      "second short-wavelength absorption band", 
      "pyrromethene PM 567", 
      "PM 567"
    ], 
    "name": "Photophysics of the analogs of pyrromethene PM 567", 
    "pagination": "291-297", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1017014354"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1134/s0030400x12070223"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1134/s0030400x12070223", 
      "https://app.dimensions.ai/details/publication/pub.1017014354"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2021-12-01T19:28", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20211201/entities/gbq_results/article/article_571.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1134/s0030400x12070223"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s0030400x12070223'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s0030400x12070223'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s0030400x12070223'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s0030400x12070223'


 

This table displays all metadata directly associated to this object as RDF triples.

124 TRIPLES      21 PREDICATES      70 URIs      62 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1134/s0030400x12070223 schema:about anzsrc-for:02
2 anzsrc-for:0205
3 schema:author N58d1e7a8f7bf4adbb546d04a77a8f8ec
4 schema:datePublished 2012-09-15
5 schema:datePublishedReg 2012-09-15
6 schema:description The spectral and luminescence properties of a number of pyrromethene (PM) dyes have been investigated. The absorption and luminescence spectra of PM molecules in different solvents are measured. The electronic structure and electronic excited states are calculated by the method of intermediate neglect of differential overlap with special spectroscopic parameterization. The rate constants of photophysical processes are estimated, and the fluorescence quantum yields are calculated. The fluorescence quantum yields of PM I and PM II molecules are found to decrease upon their excitation to the second short-wavelength absorption band. This phenomenon is interpreted.
7 schema:genre article
8 schema:inLanguage en
9 schema:isAccessibleForFree false
10 schema:isPartOf N49deb15501954024acd3ad3451b6b1aa
11 Nec6a8318c21942bab93dd4b486f57093
12 sg:journal.1294762
13 schema:keywords II molecules
14 PM 567
15 PM I
16 PM II molecules
17 PM molecules
18 absorption
19 absorption bands
20 analogues
21 band
22 constants
23 different solvents
24 differential overlap
25 dye
26 electronic excited states
27 electronic structure
28 excitation
29 excited states
30 fluorescence quantum yield
31 intermediate neglect
32 luminescence properties
33 luminescence spectra
34 method
35 molecules
36 neglect
37 number
38 overlap
39 parameterization
40 phenomenon
41 photophysical processes
42 photophysics
43 process
44 properties
45 pyrromethene PM 567
46 pyrromethene dyes
47 quantum yield
48 rate constants
49 second short-wavelength absorption band
50 short-wavelength absorption band
51 solvent
52 special spectroscopic parameterization
53 spectra
54 spectroscopic parameterization
55 state
56 structure
57 yield
58 schema:name Photophysics of the analogs of pyrromethene PM 567
59 schema:pagination 291-297
60 schema:productId N99396bb5af47487690a1df2d5eff793f
61 Nf6c892f57e2442589cb20a9b738638bd
62 schema:sameAs https://app.dimensions.ai/details/publication/pub.1017014354
63 https://doi.org/10.1134/s0030400x12070223
64 schema:sdDatePublished 2021-12-01T19:28
65 schema:sdLicense https://scigraph.springernature.com/explorer/license/
66 schema:sdPublisher N3b9879025b14432eb17e0950515d8396
67 schema:url https://doi.org/10.1134/s0030400x12070223
68 sgo:license sg:explorer/license/
69 sgo:sdDataset articles
70 rdf:type schema:ScholarlyArticle
71 N3b9879025b14432eb17e0950515d8396 schema:name Springer Nature - SN SciGraph project
72 rdf:type schema:Organization
73 N49deb15501954024acd3ad3451b6b1aa schema:volumeNumber 113
74 rdf:type schema:PublicationVolume
75 N58d1e7a8f7bf4adbb546d04a77a8f8ec rdf:first sg:person.010102045670.36
76 rdf:rest N7ea5b3bd89f9497aafc14f811b8456f1
77 N7ea5b3bd89f9497aafc14f811b8456f1 rdf:first sg:person.012340244103.07
78 rdf:rest N88829674b6db4ae0844d99c2babd46c5
79 N88829674b6db4ae0844d99c2babd46c5 rdf:first sg:person.010042754475.67
80 rdf:rest Nf458bc3977244305871fc93b1d22648f
81 N99396bb5af47487690a1df2d5eff793f schema:name doi
82 schema:value 10.1134/s0030400x12070223
83 rdf:type schema:PropertyValue
84 Nec6a8318c21942bab93dd4b486f57093 schema:issueNumber 3
85 rdf:type schema:PublicationIssue
86 Nf458bc3977244305871fc93b1d22648f rdf:first sg:person.01212220113.37
87 rdf:rest rdf:nil
88 Nf6c892f57e2442589cb20a9b738638bd schema:name dimensions_id
89 schema:value pub.1017014354
90 rdf:type schema:PropertyValue
91 anzsrc-for:02 schema:inDefinedTermSet anzsrc-for:
92 schema:name Physical Sciences
93 rdf:type schema:DefinedTerm
94 anzsrc-for:0205 schema:inDefinedTermSet anzsrc-for:
95 schema:name Optical Physics
96 rdf:type schema:DefinedTerm
97 sg:journal.1294762 schema:issn 0030-400X
98 1562-6911
99 schema:name Optics and Spectroscopy
100 schema:publisher Pleiades Publishing
101 rdf:type schema:Periodical
102 sg:person.010042754475.67 schema:affiliation grid-institutes:grid.77602.34
103 schema:familyName Aksenova
104 schema:givenName Yu. V.
105 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010042754475.67
106 rdf:type schema:Person
107 sg:person.010102045670.36 schema:affiliation grid-institutes:grid.77602.34
108 schema:familyName Sinel’nikov
109 schema:givenName A. N.
110 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010102045670.36
111 rdf:type schema:Person
112 sg:person.01212220113.37 schema:affiliation grid-institutes:grid.77602.34
113 schema:familyName Kuznetsova
114 schema:givenName R. T.
115 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01212220113.37
116 rdf:type schema:Person
117 sg:person.012340244103.07 schema:affiliation grid-institutes:grid.77602.34
118 schema:familyName Artyukhov
119 schema:givenName V. Ya.
120 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012340244103.07
121 rdf:type schema:Person
122 grid-institutes:grid.77602.34 schema:alternateName Tomsk State University, 634050, Tomsk, Russia
123 schema:name Tomsk State University, 634050, Tomsk, Russia
124 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...