Effect of the Composition and Morphology of the Active Phase of NiMoW/P-Al2O3 Catalysts with Different Mo/W Ratios on Their Activity ... View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2018-09

AUTHORS

P. S. Solmanov, N. M. Maksimov, N. N. Tomina, A. A. Pimerzin, S. P. Verevkin

ABSTRACT

A series of catalysts have been synthesized Ni–Mo–W/P-Al2O3 with different Mo: W ratios (a sample without W, Mo: W = 2: 1, Mo: W = 1: 1, Mo: W = 1: 2, and a sample without Мо) and a concentration of P2O5 in a support of 0.5 wt %. Heteropoly acids H3PMo12O40 · nH2O and H3PW12O40 · nH2O and nickel citrate were precursors of the active phase. High-resolution transmission electron microscopy and X-ray photoelectron spectroscopy were used to study the surface of the sulfide phase of the samples. Their catalytic activity was estimated in the reactions of dibenzothiophene hydrodesulfurization and naphthalene hydrogenation. A catalyst with the ratio Mo: W = 1: 1 showed the highest activity, and was characterized by the maximum concentration of atomic groups Ni–Mo–W–S, Mo–S, and W–S. More... »

PAGES

644-652

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0023158418050142

DOI

http://dx.doi.org/10.1134/s0023158418050142

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1107255270


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Samara State Technical University", 
          "id": "https://www.grid.ac/institutes/grid.445792.9", 
          "name": [
            "Samara State Technical University, 443100, Samara, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Solmanov", 
        "givenName": "P. S.", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Samara State Technical University", 
          "id": "https://www.grid.ac/institutes/grid.445792.9", 
          "name": [
            "Samara State Technical University, 443100, Samara, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Maksimov", 
        "givenName": "N. M.", 
        "id": "sg:person.012746776211.11", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012746776211.11"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Samara State Technical University", 
          "id": "https://www.grid.ac/institutes/grid.445792.9", 
          "name": [
            "Samara State Technical University, 443100, Samara, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Tomina", 
        "givenName": "N. N.", 
        "id": "sg:person.013345153743.91", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013345153743.91"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Samara State Technical University", 
          "id": "https://www.grid.ac/institutes/grid.445792.9", 
          "name": [
            "Samara State Technical University, 443100, Samara, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Pimerzin", 
        "givenName": "A. A.", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Samara State Technical University", 
          "id": "https://www.grid.ac/institutes/grid.445792.9", 
          "name": [
            "Samara State Technical University, 443100, Samara, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Verevkin", 
        "givenName": "S. P.", 
        "id": "sg:person.0733236533.48", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0733236533.48"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1016/j.catcom.2012.03.002", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1000268371"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.fuel.2007.07.020", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1001153157"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s1003-9953(10)60173-9", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1001571384"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.apsusc.2012.11.001", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1003393869"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.cattod.2007.06.041", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1004809686"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.fuproc.2011.07.020", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1011067093"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1134/s0965544115070129", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1013841178", 
          "https://doi.org/10.1134/s0965544115070129"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02066214", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1015418667", 
          "https://doi.org/10.1007/bf02066214"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02066214", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1015418667", 
          "https://doi.org/10.1007/bf02066214"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.cattod.2004.06.078", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1017241449"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.fuproc.2011.06.007", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1018601715"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.fuel.2011.12.040", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1019834242"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.fuel.2012.07.057", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1019960974"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.molcata.2006.01.018", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1020571866"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.jcat.2006.04.011", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1021920429"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.fuel.2012.05.018", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1023121259"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.jcat.2004.09.019", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1023483438"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.cattod.2009.03.017", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1024177834"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.apcata.2014.01.045", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1024926451"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.matchar.2011.04.022", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1028495141"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.cattod.2011.03.027", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1028734440"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.micromeso.2009.02.026", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1029033730"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.molcata.2003.10.018", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1029845364"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.apcata.2007.01.003", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1030158373"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1134/s096554411608017x", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1035311480", 
          "https://doi.org/10.1134/s096554411608017x"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1134/s096554411608017x", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1035311480", 
          "https://doi.org/10.1134/s096554411608017x"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.fuel.2012.11.021", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1036834077"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.fuel.2013.06.041", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1037214651"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.ijhydene.2015.10.013", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1040341977"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.fuel.2014.02.017", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1040477570"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.fuel.2012.07.005", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1041315726"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.fuproc.2013.08.023", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1041438525"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.cattod.2009.10.003", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1042422913"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02065049", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1043276660", 
          "https://doi.org/10.1007/bf02065049"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02065049", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1043276660", 
          "https://doi.org/10.1007/bf02065049"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.cattod.2010.08.021", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1043946215"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.apcatb.2010.08.018", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1044780712"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1134/s002315841402013x", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1045087731", 
          "https://doi.org/10.1134/s002315841402013x"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.jechem.2015.08.007", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1045440932"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1134/s0965544113040129", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1047015815", 
          "https://doi.org/10.1134/s0965544113040129"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.jcat.2016.09.019", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1047835214"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.apcata.2009.05.026", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1050232861"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.apcatb.2013.10.057", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1051479332"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.apcatb.2012.06.025", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1051625307"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.molcata.2010.03.008", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1053198932"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.jcat.2014.02.009", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1053530784"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/i200012a007", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055525928"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.2516/ogst:2007007", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1070870592"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1134/s1070427217070151", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1092649195", 
          "https://doi.org/10.1134/s1070427217070151"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.apcatb.2017.11.049", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1092867898"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1134/s0023158417060088", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1101303125", 
          "https://doi.org/10.1134/s0023158417060088"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1134/s0023158417060088", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1101303125", 
          "https://doi.org/10.1134/s0023158417060088"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2018-09", 
    "datePublishedReg": "2018-09-01", 
    "description": "A series of catalysts have been synthesized Ni\u2013Mo\u2013W/P-Al2O3 with different Mo: W ratios (a sample without W, Mo: W = 2: 1, Mo: W = 1: 1, Mo: W = 1: 2, and a sample without \u041c\u043e) and a concentration of P2O5 in a support of 0.5 wt %. Heteropoly acids H3PMo12O40 \u00b7 nH2O and H3PW12O40 \u00b7 nH2O and nickel citrate were precursors of the active phase. High-resolution transmission electron microscopy and X-ray photoelectron spectroscopy were used to study the surface of the sulfide phase of the samples. Their catalytic activity was estimated in the reactions of dibenzothiophene hydrodesulfurization and naphthalene hydrogenation. A catalyst with the ratio Mo: W = 1: 1 showed the highest activity, and was characterized by the maximum concentration of atomic groups Ni\u2013Mo\u2013W\u2013S, Mo\u2013S, and W\u2013S.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1134/s0023158418050142", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1136331", 
        "issn": [
          "0023-1584", 
          "0453-8811"
        ], 
        "name": "Kinetics and Catalysis", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "5", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "59"
      }
    ], 
    "name": "Effect of the Composition and Morphology of the Active Phase of NiMoW/P-Al2O3 Catalysts with Different Mo/W Ratios on Their Activity in the Reactions of Dibenzothiophene Hydrogenolysis and Naphthalene Hydrogenation", 
    "pagination": "644-652", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "52b9f6815bf8fc44aba97e66e997a67b0990fce37cd050c16c426400396e3f43"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1134/s0023158418050142"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1107255270"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1134/s0023158418050142", 
      "https://app.dimensions.ai/details/publication/pub.1107255270"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-10T15:15", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8663_00000609.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://link.springer.com/10.1134%2FS0023158418050142"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s0023158418050142'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s0023158418050142'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s0023158418050142'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s0023158418050142'


 

This table displays all metadata directly associated to this object as RDF triples.

239 TRIPLES      21 PREDICATES      75 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1134/s0023158418050142 schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author Na74b9d1a6e9d40fa94f3bdc9aee94b1e
4 schema:citation sg:pub.10.1007/bf02065049
5 sg:pub.10.1007/bf02066214
6 sg:pub.10.1134/s002315841402013x
7 sg:pub.10.1134/s0023158417060088
8 sg:pub.10.1134/s0965544113040129
9 sg:pub.10.1134/s0965544115070129
10 sg:pub.10.1134/s096554411608017x
11 sg:pub.10.1134/s1070427217070151
12 https://doi.org/10.1016/j.apcata.2007.01.003
13 https://doi.org/10.1016/j.apcata.2009.05.026
14 https://doi.org/10.1016/j.apcata.2014.01.045
15 https://doi.org/10.1016/j.apcatb.2010.08.018
16 https://doi.org/10.1016/j.apcatb.2012.06.025
17 https://doi.org/10.1016/j.apcatb.2013.10.057
18 https://doi.org/10.1016/j.apcatb.2017.11.049
19 https://doi.org/10.1016/j.apsusc.2012.11.001
20 https://doi.org/10.1016/j.catcom.2012.03.002
21 https://doi.org/10.1016/j.cattod.2004.06.078
22 https://doi.org/10.1016/j.cattod.2007.06.041
23 https://doi.org/10.1016/j.cattod.2009.03.017
24 https://doi.org/10.1016/j.cattod.2009.10.003
25 https://doi.org/10.1016/j.cattod.2010.08.021
26 https://doi.org/10.1016/j.cattod.2011.03.027
27 https://doi.org/10.1016/j.fuel.2007.07.020
28 https://doi.org/10.1016/j.fuel.2011.12.040
29 https://doi.org/10.1016/j.fuel.2012.05.018
30 https://doi.org/10.1016/j.fuel.2012.07.005
31 https://doi.org/10.1016/j.fuel.2012.07.057
32 https://doi.org/10.1016/j.fuel.2012.11.021
33 https://doi.org/10.1016/j.fuel.2013.06.041
34 https://doi.org/10.1016/j.fuel.2014.02.017
35 https://doi.org/10.1016/j.fuproc.2011.06.007
36 https://doi.org/10.1016/j.fuproc.2011.07.020
37 https://doi.org/10.1016/j.fuproc.2013.08.023
38 https://doi.org/10.1016/j.ijhydene.2015.10.013
39 https://doi.org/10.1016/j.jcat.2004.09.019
40 https://doi.org/10.1016/j.jcat.2006.04.011
41 https://doi.org/10.1016/j.jcat.2014.02.009
42 https://doi.org/10.1016/j.jcat.2016.09.019
43 https://doi.org/10.1016/j.jechem.2015.08.007
44 https://doi.org/10.1016/j.matchar.2011.04.022
45 https://doi.org/10.1016/j.micromeso.2009.02.026
46 https://doi.org/10.1016/j.molcata.2003.10.018
47 https://doi.org/10.1016/j.molcata.2006.01.018
48 https://doi.org/10.1016/j.molcata.2010.03.008
49 https://doi.org/10.1016/s1003-9953(10)60173-9
50 https://doi.org/10.1021/i200012a007
51 https://doi.org/10.2516/ogst:2007007
52 schema:datePublished 2018-09
53 schema:datePublishedReg 2018-09-01
54 schema:description A series of catalysts have been synthesized Ni–Mo–W/P-Al2O3 with different Mo: W ratios (a sample without W, Mo: W = 2: 1, Mo: W = 1: 1, Mo: W = 1: 2, and a sample without Мо) and a concentration of P2O5 in a support of 0.5 wt %. Heteropoly acids H3PMo12O40 · nH2O and H3PW12O40 · nH2O and nickel citrate were precursors of the active phase. High-resolution transmission electron microscopy and X-ray photoelectron spectroscopy were used to study the surface of the sulfide phase of the samples. Their catalytic activity was estimated in the reactions of dibenzothiophene hydrodesulfurization and naphthalene hydrogenation. A catalyst with the ratio Mo: W = 1: 1 showed the highest activity, and was characterized by the maximum concentration of atomic groups Ni–Mo–W–S, Mo–S, and W–S.
55 schema:genre research_article
56 schema:inLanguage en
57 schema:isAccessibleForFree false
58 schema:isPartOf Ne0e302e568214b829c57ba3b5d18ecc9
59 Nf3b0f54f08a34718b10eed7a8f6c4699
60 sg:journal.1136331
61 schema:name Effect of the Composition and Morphology of the Active Phase of NiMoW/P-Al2O3 Catalysts with Different Mo/W Ratios on Their Activity in the Reactions of Dibenzothiophene Hydrogenolysis and Naphthalene Hydrogenation
62 schema:pagination 644-652
63 schema:productId N11ef8126d343472889072246ad01f3c6
64 N9df29c4d24674daa815b427d7befae3c
65 Nf35bb6edee114e39847b59080a31a376
66 schema:sameAs https://app.dimensions.ai/details/publication/pub.1107255270
67 https://doi.org/10.1134/s0023158418050142
68 schema:sdDatePublished 2019-04-10T15:15
69 schema:sdLicense https://scigraph.springernature.com/explorer/license/
70 schema:sdPublisher N6572f7f57fa34a32838022876f560344
71 schema:url https://link.springer.com/10.1134%2FS0023158418050142
72 sgo:license sg:explorer/license/
73 sgo:sdDataset articles
74 rdf:type schema:ScholarlyArticle
75 N11ef8126d343472889072246ad01f3c6 schema:name readcube_id
76 schema:value 52b9f6815bf8fc44aba97e66e997a67b0990fce37cd050c16c426400396e3f43
77 rdf:type schema:PropertyValue
78 N29f749cea6cf4a798050b45d39c844e8 schema:affiliation https://www.grid.ac/institutes/grid.445792.9
79 schema:familyName Pimerzin
80 schema:givenName A. A.
81 rdf:type schema:Person
82 N4292d0d93f9640d3964957d94efe7be5 rdf:first sg:person.0733236533.48
83 rdf:rest rdf:nil
84 N4cb2dbe6290344729c83121709a9e6ef rdf:first N29f749cea6cf4a798050b45d39c844e8
85 rdf:rest N4292d0d93f9640d3964957d94efe7be5
86 N6572f7f57fa34a32838022876f560344 schema:name Springer Nature - SN SciGraph project
87 rdf:type schema:Organization
88 N869b5a02c5a84e5d91744b28bdb57b98 rdf:first sg:person.013345153743.91
89 rdf:rest N4cb2dbe6290344729c83121709a9e6ef
90 N951209cdea9f4feab705d10811d9642a schema:affiliation https://www.grid.ac/institutes/grid.445792.9
91 schema:familyName Solmanov
92 schema:givenName P. S.
93 rdf:type schema:Person
94 N9df29c4d24674daa815b427d7befae3c schema:name doi
95 schema:value 10.1134/s0023158418050142
96 rdf:type schema:PropertyValue
97 Na74b9d1a6e9d40fa94f3bdc9aee94b1e rdf:first N951209cdea9f4feab705d10811d9642a
98 rdf:rest Nd50f7524d5af4972972194764cb8b0a0
99 Nd50f7524d5af4972972194764cb8b0a0 rdf:first sg:person.012746776211.11
100 rdf:rest N869b5a02c5a84e5d91744b28bdb57b98
101 Ne0e302e568214b829c57ba3b5d18ecc9 schema:issueNumber 5
102 rdf:type schema:PublicationIssue
103 Nf35bb6edee114e39847b59080a31a376 schema:name dimensions_id
104 schema:value pub.1107255270
105 rdf:type schema:PropertyValue
106 Nf3b0f54f08a34718b10eed7a8f6c4699 schema:volumeNumber 59
107 rdf:type schema:PublicationVolume
108 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
109 schema:name Chemical Sciences
110 rdf:type schema:DefinedTerm
111 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
112 schema:name Physical Chemistry (incl. Structural)
113 rdf:type schema:DefinedTerm
114 sg:journal.1136331 schema:issn 0023-1584
115 0453-8811
116 schema:name Kinetics and Catalysis
117 rdf:type schema:Periodical
118 sg:person.012746776211.11 schema:affiliation https://www.grid.ac/institutes/grid.445792.9
119 schema:familyName Maksimov
120 schema:givenName N. M.
121 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012746776211.11
122 rdf:type schema:Person
123 sg:person.013345153743.91 schema:affiliation https://www.grid.ac/institutes/grid.445792.9
124 schema:familyName Tomina
125 schema:givenName N. N.
126 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013345153743.91
127 rdf:type schema:Person
128 sg:person.0733236533.48 schema:affiliation https://www.grid.ac/institutes/grid.445792.9
129 schema:familyName Verevkin
130 schema:givenName S. P.
131 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0733236533.48
132 rdf:type schema:Person
133 sg:pub.10.1007/bf02065049 schema:sameAs https://app.dimensions.ai/details/publication/pub.1043276660
134 https://doi.org/10.1007/bf02065049
135 rdf:type schema:CreativeWork
136 sg:pub.10.1007/bf02066214 schema:sameAs https://app.dimensions.ai/details/publication/pub.1015418667
137 https://doi.org/10.1007/bf02066214
138 rdf:type schema:CreativeWork
139 sg:pub.10.1134/s002315841402013x schema:sameAs https://app.dimensions.ai/details/publication/pub.1045087731
140 https://doi.org/10.1134/s002315841402013x
141 rdf:type schema:CreativeWork
142 sg:pub.10.1134/s0023158417060088 schema:sameAs https://app.dimensions.ai/details/publication/pub.1101303125
143 https://doi.org/10.1134/s0023158417060088
144 rdf:type schema:CreativeWork
145 sg:pub.10.1134/s0965544113040129 schema:sameAs https://app.dimensions.ai/details/publication/pub.1047015815
146 https://doi.org/10.1134/s0965544113040129
147 rdf:type schema:CreativeWork
148 sg:pub.10.1134/s0965544115070129 schema:sameAs https://app.dimensions.ai/details/publication/pub.1013841178
149 https://doi.org/10.1134/s0965544115070129
150 rdf:type schema:CreativeWork
151 sg:pub.10.1134/s096554411608017x schema:sameAs https://app.dimensions.ai/details/publication/pub.1035311480
152 https://doi.org/10.1134/s096554411608017x
153 rdf:type schema:CreativeWork
154 sg:pub.10.1134/s1070427217070151 schema:sameAs https://app.dimensions.ai/details/publication/pub.1092649195
155 https://doi.org/10.1134/s1070427217070151
156 rdf:type schema:CreativeWork
157 https://doi.org/10.1016/j.apcata.2007.01.003 schema:sameAs https://app.dimensions.ai/details/publication/pub.1030158373
158 rdf:type schema:CreativeWork
159 https://doi.org/10.1016/j.apcata.2009.05.026 schema:sameAs https://app.dimensions.ai/details/publication/pub.1050232861
160 rdf:type schema:CreativeWork
161 https://doi.org/10.1016/j.apcata.2014.01.045 schema:sameAs https://app.dimensions.ai/details/publication/pub.1024926451
162 rdf:type schema:CreativeWork
163 https://doi.org/10.1016/j.apcatb.2010.08.018 schema:sameAs https://app.dimensions.ai/details/publication/pub.1044780712
164 rdf:type schema:CreativeWork
165 https://doi.org/10.1016/j.apcatb.2012.06.025 schema:sameAs https://app.dimensions.ai/details/publication/pub.1051625307
166 rdf:type schema:CreativeWork
167 https://doi.org/10.1016/j.apcatb.2013.10.057 schema:sameAs https://app.dimensions.ai/details/publication/pub.1051479332
168 rdf:type schema:CreativeWork
169 https://doi.org/10.1016/j.apcatb.2017.11.049 schema:sameAs https://app.dimensions.ai/details/publication/pub.1092867898
170 rdf:type schema:CreativeWork
171 https://doi.org/10.1016/j.apsusc.2012.11.001 schema:sameAs https://app.dimensions.ai/details/publication/pub.1003393869
172 rdf:type schema:CreativeWork
173 https://doi.org/10.1016/j.catcom.2012.03.002 schema:sameAs https://app.dimensions.ai/details/publication/pub.1000268371
174 rdf:type schema:CreativeWork
175 https://doi.org/10.1016/j.cattod.2004.06.078 schema:sameAs https://app.dimensions.ai/details/publication/pub.1017241449
176 rdf:type schema:CreativeWork
177 https://doi.org/10.1016/j.cattod.2007.06.041 schema:sameAs https://app.dimensions.ai/details/publication/pub.1004809686
178 rdf:type schema:CreativeWork
179 https://doi.org/10.1016/j.cattod.2009.03.017 schema:sameAs https://app.dimensions.ai/details/publication/pub.1024177834
180 rdf:type schema:CreativeWork
181 https://doi.org/10.1016/j.cattod.2009.10.003 schema:sameAs https://app.dimensions.ai/details/publication/pub.1042422913
182 rdf:type schema:CreativeWork
183 https://doi.org/10.1016/j.cattod.2010.08.021 schema:sameAs https://app.dimensions.ai/details/publication/pub.1043946215
184 rdf:type schema:CreativeWork
185 https://doi.org/10.1016/j.cattod.2011.03.027 schema:sameAs https://app.dimensions.ai/details/publication/pub.1028734440
186 rdf:type schema:CreativeWork
187 https://doi.org/10.1016/j.fuel.2007.07.020 schema:sameAs https://app.dimensions.ai/details/publication/pub.1001153157
188 rdf:type schema:CreativeWork
189 https://doi.org/10.1016/j.fuel.2011.12.040 schema:sameAs https://app.dimensions.ai/details/publication/pub.1019834242
190 rdf:type schema:CreativeWork
191 https://doi.org/10.1016/j.fuel.2012.05.018 schema:sameAs https://app.dimensions.ai/details/publication/pub.1023121259
192 rdf:type schema:CreativeWork
193 https://doi.org/10.1016/j.fuel.2012.07.005 schema:sameAs https://app.dimensions.ai/details/publication/pub.1041315726
194 rdf:type schema:CreativeWork
195 https://doi.org/10.1016/j.fuel.2012.07.057 schema:sameAs https://app.dimensions.ai/details/publication/pub.1019960974
196 rdf:type schema:CreativeWork
197 https://doi.org/10.1016/j.fuel.2012.11.021 schema:sameAs https://app.dimensions.ai/details/publication/pub.1036834077
198 rdf:type schema:CreativeWork
199 https://doi.org/10.1016/j.fuel.2013.06.041 schema:sameAs https://app.dimensions.ai/details/publication/pub.1037214651
200 rdf:type schema:CreativeWork
201 https://doi.org/10.1016/j.fuel.2014.02.017 schema:sameAs https://app.dimensions.ai/details/publication/pub.1040477570
202 rdf:type schema:CreativeWork
203 https://doi.org/10.1016/j.fuproc.2011.06.007 schema:sameAs https://app.dimensions.ai/details/publication/pub.1018601715
204 rdf:type schema:CreativeWork
205 https://doi.org/10.1016/j.fuproc.2011.07.020 schema:sameAs https://app.dimensions.ai/details/publication/pub.1011067093
206 rdf:type schema:CreativeWork
207 https://doi.org/10.1016/j.fuproc.2013.08.023 schema:sameAs https://app.dimensions.ai/details/publication/pub.1041438525
208 rdf:type schema:CreativeWork
209 https://doi.org/10.1016/j.ijhydene.2015.10.013 schema:sameAs https://app.dimensions.ai/details/publication/pub.1040341977
210 rdf:type schema:CreativeWork
211 https://doi.org/10.1016/j.jcat.2004.09.019 schema:sameAs https://app.dimensions.ai/details/publication/pub.1023483438
212 rdf:type schema:CreativeWork
213 https://doi.org/10.1016/j.jcat.2006.04.011 schema:sameAs https://app.dimensions.ai/details/publication/pub.1021920429
214 rdf:type schema:CreativeWork
215 https://doi.org/10.1016/j.jcat.2014.02.009 schema:sameAs https://app.dimensions.ai/details/publication/pub.1053530784
216 rdf:type schema:CreativeWork
217 https://doi.org/10.1016/j.jcat.2016.09.019 schema:sameAs https://app.dimensions.ai/details/publication/pub.1047835214
218 rdf:type schema:CreativeWork
219 https://doi.org/10.1016/j.jechem.2015.08.007 schema:sameAs https://app.dimensions.ai/details/publication/pub.1045440932
220 rdf:type schema:CreativeWork
221 https://doi.org/10.1016/j.matchar.2011.04.022 schema:sameAs https://app.dimensions.ai/details/publication/pub.1028495141
222 rdf:type schema:CreativeWork
223 https://doi.org/10.1016/j.micromeso.2009.02.026 schema:sameAs https://app.dimensions.ai/details/publication/pub.1029033730
224 rdf:type schema:CreativeWork
225 https://doi.org/10.1016/j.molcata.2003.10.018 schema:sameAs https://app.dimensions.ai/details/publication/pub.1029845364
226 rdf:type schema:CreativeWork
227 https://doi.org/10.1016/j.molcata.2006.01.018 schema:sameAs https://app.dimensions.ai/details/publication/pub.1020571866
228 rdf:type schema:CreativeWork
229 https://doi.org/10.1016/j.molcata.2010.03.008 schema:sameAs https://app.dimensions.ai/details/publication/pub.1053198932
230 rdf:type schema:CreativeWork
231 https://doi.org/10.1016/s1003-9953(10)60173-9 schema:sameAs https://app.dimensions.ai/details/publication/pub.1001571384
232 rdf:type schema:CreativeWork
233 https://doi.org/10.1021/i200012a007 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055525928
234 rdf:type schema:CreativeWork
235 https://doi.org/10.2516/ogst:2007007 schema:sameAs https://app.dimensions.ai/details/publication/pub.1070870592
236 rdf:type schema:CreativeWork
237 https://www.grid.ac/institutes/grid.445792.9 schema:alternateName Samara State Technical University
238 schema:name Samara State Technical University, 443100, Samara, Russia
239 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...