Supported MgO–V2O5/Al2O3 catalysts for oxidative propane dehydration: Effect of the molar Mg : V ratio on the phase composition and ... View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2017-09

AUTHORS

E. D. Sushchenko, T. S. Kharlamova, T. I. Izaak, O. V. Vodyankina

ABSTRACT

The physicochemical properties of V2O5/Al2O3 and MgO–V2O5/Al2O3 supported catalysts (Mg : V = 1 : 1, 2 : 1, and 3 : 2) obtained by consecutive impregnation of the support with solutions of vanadium and magnesium precursors are studied using a complex of mutually complementary methods (XRD, Raman spectroscopy, UV–Vis spectrometry, and TPR-H2). The effect of the formation of surface magnesium vanadates of various composition and structure on the catalytic properties of the supported vanadium oxide catalysts in the oxidative dehydrogenation of propane is studied. The introduction of magnesium in the samples and an increase in its content, accompanied by a change in the structure of the surface vanadium oxide phases from polymeric VO6/VO5 species to surface metavanadate species, magnesium metavanadate, and further to magnesium divanadate, significantly affects their catalytic properties in the reaction of the oxidative dehydrogenation of propane to propylene. More... »

PAGES

630-641

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0023158417050202

DOI

http://dx.doi.org/10.1134/s0023158417050202

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1091992387


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Tomsk State University", 
          "id": "https://www.grid.ac/institutes/grid.77602.34", 
          "name": [
            "Tomsk State University, 634050, Tomsk, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Sushchenko", 
        "givenName": "E. D.", 
        "id": "sg:person.014361236602.45", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014361236602.45"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Tomsk State University", 
          "id": "https://www.grid.ac/institutes/grid.77602.34", 
          "name": [
            "Tomsk State University, 634050, Tomsk, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Kharlamova", 
        "givenName": "T. S.", 
        "id": "sg:person.015757331077.53", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015757331077.53"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Tomsk State University", 
          "id": "https://www.grid.ac/institutes/grid.77602.34", 
          "name": [
            "Tomsk State University, 634050, Tomsk, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Izaak", 
        "givenName": "T. I.", 
        "id": "sg:person.015052774661.29", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015052774661.29"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Tomsk State University", 
          "id": "https://www.grid.ac/institutes/grid.77602.34", 
          "name": [
            "Tomsk State University, 634050, Tomsk, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Vodyankina", 
        "givenName": "O. V.", 
        "id": "sg:person.013671423573.17", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013671423573.17"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1016/j.apcata.2006.04.028", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1002789119"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.jcat.2005.12.028", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1002986430"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp071409e", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1003187389"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp071409e", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1003187389"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.catcom.2012.12.012", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1003218375"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1139/v72-577", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1003377727"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.jcat.2008.09.015", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1008149020"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c3dt50692d", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1008504056"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cs5003417", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1009240607"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.jcat.2003.09.020", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1010180485"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.jcat.2013.04.020", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1011258619"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0926-860x(02)00298-3", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1011971081"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.jcat.2003.07.002", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1015280165"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.jcat.2003.07.002", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1015280165"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s10562-009-0064-2", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1017854051", 
          "https://doi.org/10.1007/s10562-009-0064-2"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s10562-009-0064-2", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1017854051", 
          "https://doi.org/10.1007/s10562-009-0064-2"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s10562-009-0064-2", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1017854051", 
          "https://doi.org/10.1007/s10562-009-0064-2"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s10562-006-0132-9", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1018659528", 
          "https://doi.org/10.1007/s10562-006-0132-9"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s10562-006-0132-9", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1018659528", 
          "https://doi.org/10.1007/s10562-006-0132-9"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c3cy00625e", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1019289161"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1006/jcat.1999.2786", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1019613787"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/qua.22389", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1021648411"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/qua.22389", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1021648411"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s10562-005-2125-5", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1022085798", 
          "https://doi.org/10.1007/s10562-005-2125-5"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s10562-005-2125-5", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1022085798", 
          "https://doi.org/10.1007/s10562-005-2125-5"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s1385-8947(03)00081-0", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1023871596"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s1385-8947(03)00081-0", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1023871596"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0926-860x(95)00056-9", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1024903219"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.cattod.2016.05.006", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1027375516"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cr5002436", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1028329741"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1023/a:1025758614040", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1028807551", 
          "https://doi.org/10.1023/a:1025758614040"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0926-860x(95)00218-9", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1031334039"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c6cy00078a", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1031750973"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0304-5102(85)85135-x", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1033834615"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c3dt50611h", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1034289267"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0926-860x(94)00253-3", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1034752121"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.jcat.2012.01.019", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1041751891"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.cattod.2007.05.009", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1041827791"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/ft9949001161", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1042223915"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.jcou.2016.08.005", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1045220253"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/9781847553287-00155", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1047349967"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.jnoncrysol.2010.04.042", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1047744705"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.jcat.2004.01.023", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1050139148"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s10562-007-9353-9", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1051352199", 
          "https://doi.org/10.1007/s10562-007-9353-9"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s10562-007-9353-9", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1051352199", 
          "https://doi.org/10.1007/s10562-007-9353-9"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1006/jcat.1996.0104", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1054488630"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cm950397j", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055417949"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cm950397j", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055417949"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/j100168a033", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055656317"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/j100168a034", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055656318"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/j100185a042", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055657658"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp040708q", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056055978"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp040708q", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056055978"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp076617l", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056074379"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp076617l", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056074379"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp9826367", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056128250"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp9826367", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056128250"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp992867t", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056131820"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp992867t", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056131820"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2017-09", 
    "datePublishedReg": "2017-09-01", 
    "description": "The physicochemical properties of V2O5/Al2O3 and MgO\u2013V2O5/Al2O3 supported catalysts (Mg : V = 1 : 1, 2 : 1, and 3 : 2) obtained by consecutive impregnation of the support with solutions of vanadium and magnesium precursors are studied using a complex of mutually complementary methods (XRD, Raman spectroscopy, UV\u2013Vis spectrometry, and TPR-H2). The effect of the formation of surface magnesium vanadates of various composition and structure on the catalytic properties of the supported vanadium oxide catalysts in the oxidative dehydrogenation of propane is studied. The introduction of magnesium in the samples and an increase in its content, accompanied by a change in the structure of the surface vanadium oxide phases from polymeric VO6/VO5 species to surface metavanadate species, magnesium metavanadate, and further to magnesium divanadate, significantly affects their catalytic properties in the reaction of the oxidative dehydrogenation of propane to propylene.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1134/s0023158417050202", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1136331", 
        "issn": [
          "0023-1584", 
          "0453-8811"
        ], 
        "name": "Kinetics and Catalysis", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "5", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "58"
      }
    ], 
    "name": "Supported MgO\u2013V2O5/Al2O3 catalysts for oxidative propane dehydration: Effect of the molar Mg : V ratio on the phase composition and catalytic properties of samples", 
    "pagination": "630-641", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "5c0388abcb61f393eb704aad73258c8936cc91eb721747ef82a6988244c087b3"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1134/s0023158417050202"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1091992387"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1134/s0023158417050202", 
      "https://app.dimensions.ai/details/publication/pub.1091992387"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-11T02:18", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8700_00000542.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://link.springer.com/10.1134%2FS0023158417050202"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s0023158417050202'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s0023158417050202'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s0023158417050202'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s0023158417050202'


 

This table displays all metadata directly associated to this object as RDF triples.

222 TRIPLES      21 PREDICATES      72 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1134/s0023158417050202 schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author N2d18a291a4084594b6ce599d25a14d00
4 schema:citation sg:pub.10.1007/s10562-005-2125-5
5 sg:pub.10.1007/s10562-006-0132-9
6 sg:pub.10.1007/s10562-007-9353-9
7 sg:pub.10.1007/s10562-009-0064-2
8 sg:pub.10.1023/a:1025758614040
9 https://doi.org/10.1002/qua.22389
10 https://doi.org/10.1006/jcat.1996.0104
11 https://doi.org/10.1006/jcat.1999.2786
12 https://doi.org/10.1016/0304-5102(85)85135-x
13 https://doi.org/10.1016/0926-860x(94)00253-3
14 https://doi.org/10.1016/0926-860x(95)00056-9
15 https://doi.org/10.1016/0926-860x(95)00218-9
16 https://doi.org/10.1016/j.apcata.2006.04.028
17 https://doi.org/10.1016/j.catcom.2012.12.012
18 https://doi.org/10.1016/j.cattod.2007.05.009
19 https://doi.org/10.1016/j.cattod.2016.05.006
20 https://doi.org/10.1016/j.jcat.2003.07.002
21 https://doi.org/10.1016/j.jcat.2003.09.020
22 https://doi.org/10.1016/j.jcat.2004.01.023
23 https://doi.org/10.1016/j.jcat.2005.12.028
24 https://doi.org/10.1016/j.jcat.2008.09.015
25 https://doi.org/10.1016/j.jcat.2012.01.019
26 https://doi.org/10.1016/j.jcat.2013.04.020
27 https://doi.org/10.1016/j.jcou.2016.08.005
28 https://doi.org/10.1016/j.jnoncrysol.2010.04.042
29 https://doi.org/10.1016/s0926-860x(02)00298-3
30 https://doi.org/10.1016/s1385-8947(03)00081-0
31 https://doi.org/10.1021/cm950397j
32 https://doi.org/10.1021/cr5002436
33 https://doi.org/10.1021/cs5003417
34 https://doi.org/10.1021/j100168a033
35 https://doi.org/10.1021/j100168a034
36 https://doi.org/10.1021/j100185a042
37 https://doi.org/10.1021/jp040708q
38 https://doi.org/10.1021/jp071409e
39 https://doi.org/10.1021/jp076617l
40 https://doi.org/10.1021/jp9826367
41 https://doi.org/10.1021/jp992867t
42 https://doi.org/10.1039/9781847553287-00155
43 https://doi.org/10.1039/c3cy00625e
44 https://doi.org/10.1039/c3dt50611h
45 https://doi.org/10.1039/c3dt50692d
46 https://doi.org/10.1039/c6cy00078a
47 https://doi.org/10.1039/ft9949001161
48 https://doi.org/10.1139/v72-577
49 schema:datePublished 2017-09
50 schema:datePublishedReg 2017-09-01
51 schema:description The physicochemical properties of V2O5/Al2O3 and MgO–V2O5/Al2O3 supported catalysts (Mg : V = 1 : 1, 2 : 1, and 3 : 2) obtained by consecutive impregnation of the support with solutions of vanadium and magnesium precursors are studied using a complex of mutually complementary methods (XRD, Raman spectroscopy, UV–Vis spectrometry, and TPR-H2). The effect of the formation of surface magnesium vanadates of various composition and structure on the catalytic properties of the supported vanadium oxide catalysts in the oxidative dehydrogenation of propane is studied. The introduction of magnesium in the samples and an increase in its content, accompanied by a change in the structure of the surface vanadium oxide phases from polymeric VO6/VO5 species to surface metavanadate species, magnesium metavanadate, and further to magnesium divanadate, significantly affects their catalytic properties in the reaction of the oxidative dehydrogenation of propane to propylene.
52 schema:genre research_article
53 schema:inLanguage en
54 schema:isAccessibleForFree false
55 schema:isPartOf N58678cdf3caf4009b992a7abba2cb9ad
56 Nd798fb6670c7476a964f12c09d4cd495
57 sg:journal.1136331
58 schema:name Supported MgO–V2O5/Al2O3 catalysts for oxidative propane dehydration: Effect of the molar Mg : V ratio on the phase composition and catalytic properties of samples
59 schema:pagination 630-641
60 schema:productId N6faec09921644be482a1d0ab8b407ccf
61 Na8b80cbf89ef434eab01f807ad1ff215
62 Nb773d39347374c76af2d3ff63d8a4a59
63 schema:sameAs https://app.dimensions.ai/details/publication/pub.1091992387
64 https://doi.org/10.1134/s0023158417050202
65 schema:sdDatePublished 2019-04-11T02:18
66 schema:sdLicense https://scigraph.springernature.com/explorer/license/
67 schema:sdPublisher N3e3e0db5e64540a6a2d2c8151cdd09a0
68 schema:url https://link.springer.com/10.1134%2FS0023158417050202
69 sgo:license sg:explorer/license/
70 sgo:sdDataset articles
71 rdf:type schema:ScholarlyArticle
72 N2d18a291a4084594b6ce599d25a14d00 rdf:first sg:person.014361236602.45
73 rdf:rest Na82daee4e9bf4939926d34f3435b3cfc
74 N3e3e0db5e64540a6a2d2c8151cdd09a0 schema:name Springer Nature - SN SciGraph project
75 rdf:type schema:Organization
76 N58678cdf3caf4009b992a7abba2cb9ad schema:issueNumber 5
77 rdf:type schema:PublicationIssue
78 N6faec09921644be482a1d0ab8b407ccf schema:name readcube_id
79 schema:value 5c0388abcb61f393eb704aad73258c8936cc91eb721747ef82a6988244c087b3
80 rdf:type schema:PropertyValue
81 N81e7a49cc3cc47f9985352f6fc1bb2de rdf:first sg:person.013671423573.17
82 rdf:rest rdf:nil
83 Na82daee4e9bf4939926d34f3435b3cfc rdf:first sg:person.015757331077.53
84 rdf:rest Naba4d87786f942138bcc37d2ad0a767f
85 Na8b80cbf89ef434eab01f807ad1ff215 schema:name doi
86 schema:value 10.1134/s0023158417050202
87 rdf:type schema:PropertyValue
88 Naba4d87786f942138bcc37d2ad0a767f rdf:first sg:person.015052774661.29
89 rdf:rest N81e7a49cc3cc47f9985352f6fc1bb2de
90 Nb773d39347374c76af2d3ff63d8a4a59 schema:name dimensions_id
91 schema:value pub.1091992387
92 rdf:type schema:PropertyValue
93 Nd798fb6670c7476a964f12c09d4cd495 schema:volumeNumber 58
94 rdf:type schema:PublicationVolume
95 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
96 schema:name Chemical Sciences
97 rdf:type schema:DefinedTerm
98 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
99 schema:name Physical Chemistry (incl. Structural)
100 rdf:type schema:DefinedTerm
101 sg:journal.1136331 schema:issn 0023-1584
102 0453-8811
103 schema:name Kinetics and Catalysis
104 rdf:type schema:Periodical
105 sg:person.013671423573.17 schema:affiliation https://www.grid.ac/institutes/grid.77602.34
106 schema:familyName Vodyankina
107 schema:givenName O. V.
108 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013671423573.17
109 rdf:type schema:Person
110 sg:person.014361236602.45 schema:affiliation https://www.grid.ac/institutes/grid.77602.34
111 schema:familyName Sushchenko
112 schema:givenName E. D.
113 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014361236602.45
114 rdf:type schema:Person
115 sg:person.015052774661.29 schema:affiliation https://www.grid.ac/institutes/grid.77602.34
116 schema:familyName Izaak
117 schema:givenName T. I.
118 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015052774661.29
119 rdf:type schema:Person
120 sg:person.015757331077.53 schema:affiliation https://www.grid.ac/institutes/grid.77602.34
121 schema:familyName Kharlamova
122 schema:givenName T. S.
123 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015757331077.53
124 rdf:type schema:Person
125 sg:pub.10.1007/s10562-005-2125-5 schema:sameAs https://app.dimensions.ai/details/publication/pub.1022085798
126 https://doi.org/10.1007/s10562-005-2125-5
127 rdf:type schema:CreativeWork
128 sg:pub.10.1007/s10562-006-0132-9 schema:sameAs https://app.dimensions.ai/details/publication/pub.1018659528
129 https://doi.org/10.1007/s10562-006-0132-9
130 rdf:type schema:CreativeWork
131 sg:pub.10.1007/s10562-007-9353-9 schema:sameAs https://app.dimensions.ai/details/publication/pub.1051352199
132 https://doi.org/10.1007/s10562-007-9353-9
133 rdf:type schema:CreativeWork
134 sg:pub.10.1007/s10562-009-0064-2 schema:sameAs https://app.dimensions.ai/details/publication/pub.1017854051
135 https://doi.org/10.1007/s10562-009-0064-2
136 rdf:type schema:CreativeWork
137 sg:pub.10.1023/a:1025758614040 schema:sameAs https://app.dimensions.ai/details/publication/pub.1028807551
138 https://doi.org/10.1023/a:1025758614040
139 rdf:type schema:CreativeWork
140 https://doi.org/10.1002/qua.22389 schema:sameAs https://app.dimensions.ai/details/publication/pub.1021648411
141 rdf:type schema:CreativeWork
142 https://doi.org/10.1006/jcat.1996.0104 schema:sameAs https://app.dimensions.ai/details/publication/pub.1054488630
143 rdf:type schema:CreativeWork
144 https://doi.org/10.1006/jcat.1999.2786 schema:sameAs https://app.dimensions.ai/details/publication/pub.1019613787
145 rdf:type schema:CreativeWork
146 https://doi.org/10.1016/0304-5102(85)85135-x schema:sameAs https://app.dimensions.ai/details/publication/pub.1033834615
147 rdf:type schema:CreativeWork
148 https://doi.org/10.1016/0926-860x(94)00253-3 schema:sameAs https://app.dimensions.ai/details/publication/pub.1034752121
149 rdf:type schema:CreativeWork
150 https://doi.org/10.1016/0926-860x(95)00056-9 schema:sameAs https://app.dimensions.ai/details/publication/pub.1024903219
151 rdf:type schema:CreativeWork
152 https://doi.org/10.1016/0926-860x(95)00218-9 schema:sameAs https://app.dimensions.ai/details/publication/pub.1031334039
153 rdf:type schema:CreativeWork
154 https://doi.org/10.1016/j.apcata.2006.04.028 schema:sameAs https://app.dimensions.ai/details/publication/pub.1002789119
155 rdf:type schema:CreativeWork
156 https://doi.org/10.1016/j.catcom.2012.12.012 schema:sameAs https://app.dimensions.ai/details/publication/pub.1003218375
157 rdf:type schema:CreativeWork
158 https://doi.org/10.1016/j.cattod.2007.05.009 schema:sameAs https://app.dimensions.ai/details/publication/pub.1041827791
159 rdf:type schema:CreativeWork
160 https://doi.org/10.1016/j.cattod.2016.05.006 schema:sameAs https://app.dimensions.ai/details/publication/pub.1027375516
161 rdf:type schema:CreativeWork
162 https://doi.org/10.1016/j.jcat.2003.07.002 schema:sameAs https://app.dimensions.ai/details/publication/pub.1015280165
163 rdf:type schema:CreativeWork
164 https://doi.org/10.1016/j.jcat.2003.09.020 schema:sameAs https://app.dimensions.ai/details/publication/pub.1010180485
165 rdf:type schema:CreativeWork
166 https://doi.org/10.1016/j.jcat.2004.01.023 schema:sameAs https://app.dimensions.ai/details/publication/pub.1050139148
167 rdf:type schema:CreativeWork
168 https://doi.org/10.1016/j.jcat.2005.12.028 schema:sameAs https://app.dimensions.ai/details/publication/pub.1002986430
169 rdf:type schema:CreativeWork
170 https://doi.org/10.1016/j.jcat.2008.09.015 schema:sameAs https://app.dimensions.ai/details/publication/pub.1008149020
171 rdf:type schema:CreativeWork
172 https://doi.org/10.1016/j.jcat.2012.01.019 schema:sameAs https://app.dimensions.ai/details/publication/pub.1041751891
173 rdf:type schema:CreativeWork
174 https://doi.org/10.1016/j.jcat.2013.04.020 schema:sameAs https://app.dimensions.ai/details/publication/pub.1011258619
175 rdf:type schema:CreativeWork
176 https://doi.org/10.1016/j.jcou.2016.08.005 schema:sameAs https://app.dimensions.ai/details/publication/pub.1045220253
177 rdf:type schema:CreativeWork
178 https://doi.org/10.1016/j.jnoncrysol.2010.04.042 schema:sameAs https://app.dimensions.ai/details/publication/pub.1047744705
179 rdf:type schema:CreativeWork
180 https://doi.org/10.1016/s0926-860x(02)00298-3 schema:sameAs https://app.dimensions.ai/details/publication/pub.1011971081
181 rdf:type schema:CreativeWork
182 https://doi.org/10.1016/s1385-8947(03)00081-0 schema:sameAs https://app.dimensions.ai/details/publication/pub.1023871596
183 rdf:type schema:CreativeWork
184 https://doi.org/10.1021/cm950397j schema:sameAs https://app.dimensions.ai/details/publication/pub.1055417949
185 rdf:type schema:CreativeWork
186 https://doi.org/10.1021/cr5002436 schema:sameAs https://app.dimensions.ai/details/publication/pub.1028329741
187 rdf:type schema:CreativeWork
188 https://doi.org/10.1021/cs5003417 schema:sameAs https://app.dimensions.ai/details/publication/pub.1009240607
189 rdf:type schema:CreativeWork
190 https://doi.org/10.1021/j100168a033 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055656317
191 rdf:type schema:CreativeWork
192 https://doi.org/10.1021/j100168a034 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055656318
193 rdf:type schema:CreativeWork
194 https://doi.org/10.1021/j100185a042 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055657658
195 rdf:type schema:CreativeWork
196 https://doi.org/10.1021/jp040708q schema:sameAs https://app.dimensions.ai/details/publication/pub.1056055978
197 rdf:type schema:CreativeWork
198 https://doi.org/10.1021/jp071409e schema:sameAs https://app.dimensions.ai/details/publication/pub.1003187389
199 rdf:type schema:CreativeWork
200 https://doi.org/10.1021/jp076617l schema:sameAs https://app.dimensions.ai/details/publication/pub.1056074379
201 rdf:type schema:CreativeWork
202 https://doi.org/10.1021/jp9826367 schema:sameAs https://app.dimensions.ai/details/publication/pub.1056128250
203 rdf:type schema:CreativeWork
204 https://doi.org/10.1021/jp992867t schema:sameAs https://app.dimensions.ai/details/publication/pub.1056131820
205 rdf:type schema:CreativeWork
206 https://doi.org/10.1039/9781847553287-00155 schema:sameAs https://app.dimensions.ai/details/publication/pub.1047349967
207 rdf:type schema:CreativeWork
208 https://doi.org/10.1039/c3cy00625e schema:sameAs https://app.dimensions.ai/details/publication/pub.1019289161
209 rdf:type schema:CreativeWork
210 https://doi.org/10.1039/c3dt50611h schema:sameAs https://app.dimensions.ai/details/publication/pub.1034289267
211 rdf:type schema:CreativeWork
212 https://doi.org/10.1039/c3dt50692d schema:sameAs https://app.dimensions.ai/details/publication/pub.1008504056
213 rdf:type schema:CreativeWork
214 https://doi.org/10.1039/c6cy00078a schema:sameAs https://app.dimensions.ai/details/publication/pub.1031750973
215 rdf:type schema:CreativeWork
216 https://doi.org/10.1039/ft9949001161 schema:sameAs https://app.dimensions.ai/details/publication/pub.1042223915
217 rdf:type schema:CreativeWork
218 https://doi.org/10.1139/v72-577 schema:sameAs https://app.dimensions.ai/details/publication/pub.1003377727
219 rdf:type schema:CreativeWork
220 https://www.grid.ac/institutes/grid.77602.34 schema:alternateName Tomsk State University
221 schema:name Tomsk State University, 634050, Tomsk, Russia
222 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...