Ring-opening metathesis polymerization (ROMP) of fullerene-containing monomers in the presence of a first-generation Grubbs catalyst View Full Text


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Article Info

DATE

2017-03

AUTHORS

Yu. N. Biglova, A. G. Mustafin, S. A. Torosyan, R. Z. Biglova, M. S. Miftakhov

ABSTRACT

New norbornene-type monomers containing covalently bound C60 fullerene have been obtained. In the presence of the 1st generation Grubbs catalyst [(PCy3)2Cl2RuCHPh] (Cy is cyclohexyl), these monomers smoothly undergo homopolymerization and copolymerization with parent fullerene-free monomers. The homopolymers are insoluble in common organic solvents, while the copolymers obtained at different molar ratios to their fullerene-free analogues are very soluble in organic solvents and can be suitable for the preparation of thin films. More... »

PAGES

111-121

References to SciGraph publications

  • 2014-02. New monomers for fullerene-containing polymers in RUSSIAN JOURNAL OF ORGANIC CHEMISTRY
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1134/s0023158417020021

    DOI

    http://dx.doi.org/10.1134/s0023158417020021

    DIMENSIONS

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