Role of the chemical mechanism in the temperature dependence of the rate of gas combustion reactions View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2015-01

AUTHORS

V. V. Azatyan

ABSTRACT

The determining role of the kinetic mechanism in the temperature dependence of reaction rates is demonstrated. New evidence is presented to prove that the branched chain nature of gas combustion at low pressures and under isothermal conditions, discovered by N.N. Semenov, persists in combustion processes at elevated pressures under any temperature and macrokinetic conditions. It is noted that the temperature dependence of the rate constants of bimolecular reactions weakens with an increasing activation energy. More... »

PAGES

1-11

Journal

TITLE

Kinetics and Catalysis

ISSUE

1

VOLUME

56

Author Affiliations

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0023158415010024

DOI

http://dx.doi.org/10.1134/s0023158415010024

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1015168865


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