Solvent effect on the kinetics of the free-radical polymerization of styrene in the presence of fullerene C60 View Full Text


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Article Info

DATE

2014-01

AUTHORS

R. Kh. Yumagulova, N. A. Medvedeva, S. I. Kuznetsov, V. A. Kraikin, S. V. Kolesov

ABSTRACT

The induction period in the kinetic curves of styrene polymerization in the presence of fullerene C60 was found to increase significantly at a solvent (benzene, toluene, ortho-dichlorobenzene, CCl4) concentration of ≥50 mol %. The free-radical polymerization rates of styrene in the presence of fullerene C60 and solvents, the ratio of chain propagation and termination rate constants kp/k01/2, and the stoichiometric inhibition coefficient were determined. More... »

PAGES

64-68

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0023158414010182

DOI

http://dx.doi.org/10.1134/s0023158414010182

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1012261939


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