Kinetic regularities of catalytic ethylene polymerization on single- and multi-site cobalt and vanadium bis(imino)pyridine complexes View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2013-07

AUTHORS

A. A. Barabanov, N. V. Semikolenova, M. A. Mats’ko, V. A. Zakharov

ABSTRACT

The number of active centers Cp in the homogeneous complexes LCoCl2 and LVCl3 (L = 2,6-(2,6-R2C6H3N=CMe)2C5H3N; R = Me, Et, tBu) and the propagation rate constants kp have been determined by the radioactive 14CO quenching of ethylene polymerization on these complexes in the presence of the methylaluminoxane (MAO) activator. For the systems studied, a significant portion of the initial complex (up to 70%) transforms into polymerization-active centers. The catalysts based on the cobalt complexes are single-site, and the constant kp in these systems is independent of the volume of substituent R in the ligand, being (2.4−3.5) × 103 L mol−1 s−1 at 35°C. The much larger molecular weight of the polymer formed on the complex with the tert-butyl substituent in the aryl rings of the ligand compared to the product formed on the complex with the methyl substituent is due to the substantial (∼11-fold) decrease in the rate constant of chain transfer to the monomer. At the early stages of the reaction (before 5 min), the vanadium complexes contain active centers of one type only, for which kp = 2.6 × 103 L mol−1 s−1 at 35°C. An increase in the polymerization time to 20 min results in the appearance, in the vanadium systems, of new, substantially less reactive centers on which high-molecular-weight polyethylene forms. The number of active centers Cp in the 2,5-tBu2LCoCl2 and 2,6-Et2LVCl3 systems with the MAO activator increases as the polymerization temperature is raised from 25 to 60°C. The activation energies of the chain propagation reaction (Ep) have been calculated. The value of Ep for complex 2,5-tBu2LCoCl2 is 4.5 kcal/mol. It is assumed that the so-called “dormant” centers form in ethylene polymerization on the 2,6-Et2LVCl3 complex, and their proportion increases with a decrease in the polymerization temperature. Probably, the anomalously high value Ep = 14.2 kcal/mol for the vanadium system is explained by the formation of these “dormant” centers. More... »

PAGES

475-480

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0023158413040022

DOI

http://dx.doi.org/10.1134/s0023158413040022

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1031885595


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0303", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Macromolecular and Materials Chemistry", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Boreskov Institute of Catalysis", 
          "id": "https://www.grid.ac/institutes/grid.418421.a", 
          "name": [
            "Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Barabanov", 
        "givenName": "A. A.", 
        "id": "sg:person.014155662347.03", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014155662347.03"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Boreskov Institute of Catalysis", 
          "id": "https://www.grid.ac/institutes/grid.418421.a", 
          "name": [
            "Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Semikolenova", 
        "givenName": "N. V.", 
        "id": "sg:person.016271117563.11", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016271117563.11"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Boreskov Institute of Catalysis", 
          "id": "https://www.grid.ac/institutes/grid.418421.a", 
          "name": [
            "Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Mats\u2019ko", 
        "givenName": "M. A.", 
        "id": "sg:person.011506316054.20", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011506316054.20"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Boreskov Institute of Catalysis", 
          "id": "https://www.grid.ac/institutes/grid.418421.a", 
          "name": [
            "Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Zakharov", 
        "givenName": "V. A.", 
        "id": "sg:person.014214146645.68", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014214146645.68"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1016/j.molcata.2004.07.015", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1005578740"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.cattod.2004.06.057", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1010917617"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/1521-3773(20011217)40:24<4719::aid-anie4719>3.0.co;2-o", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1019213221"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/macp.200800376", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1019734237"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s1381-1169(01)00476-9", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1023155398"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/pola.22972", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1028340340"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/marc.200300022", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1031206970"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.cattod.2009.01.022", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1035821018"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/app.21488", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1038058117"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.jorganchem.2004.11.029", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1040992045"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf03219008", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1042734574", 
          "https://doi.org/10.1007/bf03219008"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/a801933i", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1044366356"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja990449w", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1046377135"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/macp.200500310", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1048394597"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/macp.200500310", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1048394597"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.molcata.2004.07.014", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1051932483"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja9802100", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055869378"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja990263x", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055871648"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/om900490b", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056282163"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2013-07", 
    "datePublishedReg": "2013-07-01", 
    "description": "The number of active centers Cp in the homogeneous complexes LCoCl2 and LVCl3 (L = 2,6-(2,6-R2C6H3N=CMe)2C5H3N; R = Me, Et, tBu) and the propagation rate constants kp have been determined by the radioactive 14CO quenching of ethylene polymerization on these complexes in the presence of the methylaluminoxane (MAO) activator. For the systems studied, a significant portion of the initial complex (up to 70%) transforms into polymerization-active centers. The catalysts based on the cobalt complexes are single-site, and the constant kp in these systems is independent of the volume of substituent R in the ligand, being (2.4\u22123.5) \u00d7 103 L mol\u22121 s\u22121 at 35\u00b0C. The much larger molecular weight of the polymer formed on the complex with the tert-butyl substituent in the aryl rings of the ligand compared to the product formed on the complex with the methyl substituent is due to the substantial (\u223c11-fold) decrease in the rate constant of chain transfer to the monomer. At the early stages of the reaction (before 5 min), the vanadium complexes contain active centers of one type only, for which kp = 2.6 \u00d7 103 L mol\u22121 s\u22121 at 35\u00b0C. An increase in the polymerization time to 20 min results in the appearance, in the vanadium systems, of new, substantially less reactive centers on which high-molecular-weight polyethylene forms. The number of active centers Cp in the 2,5-tBu2LCoCl2 and 2,6-Et2LVCl3 systems with the MAO activator increases as the polymerization temperature is raised from 25 to 60\u00b0C. The activation energies of the chain propagation reaction (Ep) have been calculated. The value of Ep for complex 2,5-tBu2LCoCl2 is 4.5 kcal/mol. It is assumed that the so-called \u201cdormant\u201d centers form in ethylene polymerization on the 2,6-Et2LVCl3 complex, and their proportion increases with a decrease in the polymerization temperature. Probably, the anomalously high value Ep = 14.2 kcal/mol for the vanadium system is explained by the formation of these \u201cdormant\u201d centers.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1134/s0023158413040022", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1136331", 
        "issn": [
          "0023-1584", 
          "0453-8811"
        ], 
        "name": "Kinetics and Catalysis", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "4", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "54"
      }
    ], 
    "name": "Kinetic regularities of catalytic ethylene polymerization on single- and multi-site cobalt and vanadium bis(imino)pyridine complexes", 
    "pagination": "475-480", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "97e542efdfc4c64947cea41447f6f1e8c66af796aec015618e82b8a33bff9a05"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1134/s0023158413040022"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1031885595"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1134/s0023158413040022", 
      "https://app.dimensions.ai/details/publication/pub.1031885595"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-11T01:04", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8697_00000500.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1134/S0023158413040022"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s0023158413040022'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s0023158413040022'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s0023158413040022'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s0023158413040022'


 

This table displays all metadata directly associated to this object as RDF triples.

137 TRIPLES      21 PREDICATES      45 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1134/s0023158413040022 schema:about anzsrc-for:03
2 anzsrc-for:0303
3 schema:author Na496b6648301495cbb3d72493ab6e9ee
4 schema:citation sg:pub.10.1007/bf03219008
5 https://doi.org/10.1002/1521-3773(20011217)40:24<4719::aid-anie4719>3.0.co;2-o
6 https://doi.org/10.1002/app.21488
7 https://doi.org/10.1002/macp.200500310
8 https://doi.org/10.1002/macp.200800376
9 https://doi.org/10.1002/marc.200300022
10 https://doi.org/10.1002/pola.22972
11 https://doi.org/10.1016/j.cattod.2004.06.057
12 https://doi.org/10.1016/j.cattod.2009.01.022
13 https://doi.org/10.1016/j.jorganchem.2004.11.029
14 https://doi.org/10.1016/j.molcata.2004.07.014
15 https://doi.org/10.1016/j.molcata.2004.07.015
16 https://doi.org/10.1016/s1381-1169(01)00476-9
17 https://doi.org/10.1021/ja9802100
18 https://doi.org/10.1021/ja990263x
19 https://doi.org/10.1021/ja990449w
20 https://doi.org/10.1021/om900490b
21 https://doi.org/10.1039/a801933i
22 schema:datePublished 2013-07
23 schema:datePublishedReg 2013-07-01
24 schema:description The number of active centers Cp in the homogeneous complexes LCoCl2 and LVCl3 (L = 2,6-(2,6-R2C6H3N=CMe)2C5H3N; R = Me, Et, tBu) and the propagation rate constants kp have been determined by the radioactive 14CO quenching of ethylene polymerization on these complexes in the presence of the methylaluminoxane (MAO) activator. For the systems studied, a significant portion of the initial complex (up to 70%) transforms into polymerization-active centers. The catalysts based on the cobalt complexes are single-site, and the constant kp in these systems is independent of the volume of substituent R in the ligand, being (2.4−3.5) × 103 L mol−1 s−1 at 35°C. The much larger molecular weight of the polymer formed on the complex with the tert-butyl substituent in the aryl rings of the ligand compared to the product formed on the complex with the methyl substituent is due to the substantial (∼11-fold) decrease in the rate constant of chain transfer to the monomer. At the early stages of the reaction (before 5 min), the vanadium complexes contain active centers of one type only, for which kp = 2.6 × 103 L mol−1 s−1 at 35°C. An increase in the polymerization time to 20 min results in the appearance, in the vanadium systems, of new, substantially less reactive centers on which high-molecular-weight polyethylene forms. The number of active centers Cp in the 2,5-tBu2LCoCl2 and 2,6-Et2LVCl3 systems with the MAO activator increases as the polymerization temperature is raised from 25 to 60°C. The activation energies of the chain propagation reaction (Ep) have been calculated. The value of Ep for complex 2,5-tBu2LCoCl2 is 4.5 kcal/mol. It is assumed that the so-called “dormant” centers form in ethylene polymerization on the 2,6-Et2LVCl3 complex, and their proportion increases with a decrease in the polymerization temperature. Probably, the anomalously high value Ep = 14.2 kcal/mol for the vanadium system is explained by the formation of these “dormant” centers.
25 schema:genre research_article
26 schema:inLanguage en
27 schema:isAccessibleForFree false
28 schema:isPartOf Ncc8fd8d6a66f4d4b9d0fa29951456ea3
29 Nf52dbc6ce35440238d437c6f9643ec9a
30 sg:journal.1136331
31 schema:name Kinetic regularities of catalytic ethylene polymerization on single- and multi-site cobalt and vanadium bis(imino)pyridine complexes
32 schema:pagination 475-480
33 schema:productId N07a442f249324ea2a684536486f9b12f
34 N646c0a5506b5477a94617b2cad17025d
35 N6a929cd3c6554f668825bff9f55d3b2a
36 schema:sameAs https://app.dimensions.ai/details/publication/pub.1031885595
37 https://doi.org/10.1134/s0023158413040022
38 schema:sdDatePublished 2019-04-11T01:04
39 schema:sdLicense https://scigraph.springernature.com/explorer/license/
40 schema:sdPublisher N0b29e593fe2e46b3925a019ae536f3d5
41 schema:url http://link.springer.com/10.1134/S0023158413040022
42 sgo:license sg:explorer/license/
43 sgo:sdDataset articles
44 rdf:type schema:ScholarlyArticle
45 N07a442f249324ea2a684536486f9b12f schema:name dimensions_id
46 schema:value pub.1031885595
47 rdf:type schema:PropertyValue
48 N0b29e593fe2e46b3925a019ae536f3d5 schema:name Springer Nature - SN SciGraph project
49 rdf:type schema:Organization
50 N5e39cdab6f3e41d3a0c45107f8835aac rdf:first sg:person.011506316054.20
51 rdf:rest Ndb5506b214db4d62a60f6a9c159c474e
52 N646c0a5506b5477a94617b2cad17025d schema:name doi
53 schema:value 10.1134/s0023158413040022
54 rdf:type schema:PropertyValue
55 N6a929cd3c6554f668825bff9f55d3b2a schema:name readcube_id
56 schema:value 97e542efdfc4c64947cea41447f6f1e8c66af796aec015618e82b8a33bff9a05
57 rdf:type schema:PropertyValue
58 Na496b6648301495cbb3d72493ab6e9ee rdf:first sg:person.014155662347.03
59 rdf:rest Nd21a438462174833881efb650f13f354
60 Ncc8fd8d6a66f4d4b9d0fa29951456ea3 schema:issueNumber 4
61 rdf:type schema:PublicationIssue
62 Nd21a438462174833881efb650f13f354 rdf:first sg:person.016271117563.11
63 rdf:rest N5e39cdab6f3e41d3a0c45107f8835aac
64 Ndb5506b214db4d62a60f6a9c159c474e rdf:first sg:person.014214146645.68
65 rdf:rest rdf:nil
66 Nf52dbc6ce35440238d437c6f9643ec9a schema:volumeNumber 54
67 rdf:type schema:PublicationVolume
68 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
69 schema:name Chemical Sciences
70 rdf:type schema:DefinedTerm
71 anzsrc-for:0303 schema:inDefinedTermSet anzsrc-for:
72 schema:name Macromolecular and Materials Chemistry
73 rdf:type schema:DefinedTerm
74 sg:journal.1136331 schema:issn 0023-1584
75 0453-8811
76 schema:name Kinetics and Catalysis
77 rdf:type schema:Periodical
78 sg:person.011506316054.20 schema:affiliation https://www.grid.ac/institutes/grid.418421.a
79 schema:familyName Mats’ko
80 schema:givenName M. A.
81 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011506316054.20
82 rdf:type schema:Person
83 sg:person.014155662347.03 schema:affiliation https://www.grid.ac/institutes/grid.418421.a
84 schema:familyName Barabanov
85 schema:givenName A. A.
86 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014155662347.03
87 rdf:type schema:Person
88 sg:person.014214146645.68 schema:affiliation https://www.grid.ac/institutes/grid.418421.a
89 schema:familyName Zakharov
90 schema:givenName V. A.
91 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014214146645.68
92 rdf:type schema:Person
93 sg:person.016271117563.11 schema:affiliation https://www.grid.ac/institutes/grid.418421.a
94 schema:familyName Semikolenova
95 schema:givenName N. V.
96 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016271117563.11
97 rdf:type schema:Person
98 sg:pub.10.1007/bf03219008 schema:sameAs https://app.dimensions.ai/details/publication/pub.1042734574
99 https://doi.org/10.1007/bf03219008
100 rdf:type schema:CreativeWork
101 https://doi.org/10.1002/1521-3773(20011217)40:24<4719::aid-anie4719>3.0.co;2-o schema:sameAs https://app.dimensions.ai/details/publication/pub.1019213221
102 rdf:type schema:CreativeWork
103 https://doi.org/10.1002/app.21488 schema:sameAs https://app.dimensions.ai/details/publication/pub.1038058117
104 rdf:type schema:CreativeWork
105 https://doi.org/10.1002/macp.200500310 schema:sameAs https://app.dimensions.ai/details/publication/pub.1048394597
106 rdf:type schema:CreativeWork
107 https://doi.org/10.1002/macp.200800376 schema:sameAs https://app.dimensions.ai/details/publication/pub.1019734237
108 rdf:type schema:CreativeWork
109 https://doi.org/10.1002/marc.200300022 schema:sameAs https://app.dimensions.ai/details/publication/pub.1031206970
110 rdf:type schema:CreativeWork
111 https://doi.org/10.1002/pola.22972 schema:sameAs https://app.dimensions.ai/details/publication/pub.1028340340
112 rdf:type schema:CreativeWork
113 https://doi.org/10.1016/j.cattod.2004.06.057 schema:sameAs https://app.dimensions.ai/details/publication/pub.1010917617
114 rdf:type schema:CreativeWork
115 https://doi.org/10.1016/j.cattod.2009.01.022 schema:sameAs https://app.dimensions.ai/details/publication/pub.1035821018
116 rdf:type schema:CreativeWork
117 https://doi.org/10.1016/j.jorganchem.2004.11.029 schema:sameAs https://app.dimensions.ai/details/publication/pub.1040992045
118 rdf:type schema:CreativeWork
119 https://doi.org/10.1016/j.molcata.2004.07.014 schema:sameAs https://app.dimensions.ai/details/publication/pub.1051932483
120 rdf:type schema:CreativeWork
121 https://doi.org/10.1016/j.molcata.2004.07.015 schema:sameAs https://app.dimensions.ai/details/publication/pub.1005578740
122 rdf:type schema:CreativeWork
123 https://doi.org/10.1016/s1381-1169(01)00476-9 schema:sameAs https://app.dimensions.ai/details/publication/pub.1023155398
124 rdf:type schema:CreativeWork
125 https://doi.org/10.1021/ja9802100 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055869378
126 rdf:type schema:CreativeWork
127 https://doi.org/10.1021/ja990263x schema:sameAs https://app.dimensions.ai/details/publication/pub.1055871648
128 rdf:type schema:CreativeWork
129 https://doi.org/10.1021/ja990449w schema:sameAs https://app.dimensions.ai/details/publication/pub.1046377135
130 rdf:type schema:CreativeWork
131 https://doi.org/10.1021/om900490b schema:sameAs https://app.dimensions.ai/details/publication/pub.1056282163
132 rdf:type schema:CreativeWork
133 https://doi.org/10.1039/a801933i schema:sameAs https://app.dimensions.ai/details/publication/pub.1044366356
134 rdf:type schema:CreativeWork
135 https://www.grid.ac/institutes/grid.418421.a schema:alternateName Boreskov Institute of Catalysis
136 schema:name Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia
137 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...