Cobalt salts of decamolybdodicobaltic acid as precursors of the highly reactive type II CoMoS phase in hydrorefining catalysts View Full Text


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Article Info

DATE

2011-11-30

AUTHORS

P. A. Nikul’shin, A. V. Mozhaev, A. A. Pimerzin, N. N. Tomina, V. V. Konovalov, V. M. Kogan

ABSTRACT

Catalysts have been synthesized using the Anderson polyoxometalates (POMs) (NH4)4[Ni(OH)6Mo6O18] (NiMo6POM), (NH4)6[Co2Mo10O38H4] · 7H2O (Co2Mo10POM), and H6[Co2Mo10O38H4] (Co2Mo10HPA) as the precursors and hydrogen peroxide as the solvent. The catalysts have been characterized by low-temperature nitrogen adsorption, XPS, and HRTEM. Their catalytic properties have been tested in thiophene hydrodesulfurization and in the hydrodesulfurization and hydrogenation of components of diesel oil. The active phase of the catalysts synthesized using the POMs is the type II CoMoS phase in which the mean plate length is 3.6–3.9 nm and the mean number of MoS2 plate per plate packet is 1.8–2.0. Use of hydrogen peroxide provides an efficient means to reduce the proportion of Co2+ promoter atoms surrounded by oxygen in the case of an impregnating solution containing both an ammonium salt of a heteropoly acid and a Co2+ salt. In the catalysts synthesized using cobalt salts of Co2Mo10HPA, the support surface contains the multilayer type II CoMoS phase and cobalt sulfides. These catalyst show high catalytic properties in thiophene hydrogenolysis and diesel oil hydrorefining. Models are suggested for the catalysts synthesized using Anderson POMs. More... »

PAGES

862-875

References to SciGraph publications

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  • 2004-01. Influence of Cobalt Content on the Hydrotreatment Catalytic Activity of CoMo6/γ-Al2O3 Heteropolyoxomolybdate-Based Catalyst in CATALYSIS LETTERS
  • 2006-12. Support effect on the properties of iron–molybdenum hydrodesulfurization catalysts in CATALYSIS LETTERS
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  • 2008-09-23. Study of the Individual Reactions of Hydrodesulphurization of Dibenzothiophene and Hydrogenation of 2-Methylnaphthalene on ZnNiMo/γ-Alumina Catalysts in CATALYSIS LETTERS
  • 2008-09-30. Influence of the nature of molybdenum compounds on the activity of Mo/γ-Al2O3 and NiMo/γ-Al2O3 hydrotreating catalysts in KINETICS AND CATALYSIS
  • 2009-03. Thiophene hydrodesulfurization and diesel fuel hydrorefining activities of XMo6(S)/γ-Al2O3 and Ni-XMo6(S)/γ-Al2O3 (X = Al, Ga, In, Fe, Co, and Ni) catalysts in KINETICS AND CATALYSIS
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    http://scigraph.springernature.com/pub.10.1134/s0023158411060152

    DOI

    http://dx.doi.org/10.1134/s0023158411060152

    DIMENSIONS

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