Ontology type: schema:ScholarlyArticle
2010-06
AUTHORSA. A. Azatyan, Z. S. Andrianova, A. N. Ivanova
ABSTRACTIt is demonstrated by simultaneous analysis of experimental data and the results of numerical simulation that, at 100 kPa, the H2/O2 mixture self-ignites only owing to the occurrence of a chain avalanche. Self-heating becomes significant in the course of chain combustion and strengthens the chain avalanche. The accelerating decomposition of H2O2, which results from the reaction between HO2• and H2, contributes to chain branching and determines the character of the chain thermal explosion. The role of the HO2• radical depends on the chain process conditions, consisting of chain termination as a result of the partial loss of HO2• at the initial self-acceleration stage, H atom regeneration, and participation in the second branched cycle under conditions of accelerated H2O2 decomposition. More... »
PAGES337-347
http://scigraph.springernature.com/pub.10.1134/s002315841003002x
DOIhttp://dx.doi.org/10.1134/s002315841003002x
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