Thiophene hydrodesulfurization and diesel fuel hydrorefining activities of XMo6(S)/γ-Al2O3 and Ni-XMo6(S)/γ-Al2O3 (X = Al, Ga, In, Fe, Co, and Ni) ... View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2009-03

AUTHORS

N. N. Tomina, P. A. Nikul’shin, V. S. Tsvetkov, A. A. Pimerzin

ABSTRACT

XMo6(S)/γ-Al2O3 and Ni-XMo6(S)/γ-Al2O3 catalysts based on Anderson heteropoly compounds (HPCs), where X = Al, Ga, In, Fe, Co, and Ni, were synthesized. The nature of the precursor HPC determines the activity of the catalysts in thiophene hydrogenolysis and diesel fuel hydrorefining in a flow-through setup. The activity of Ni-XMo6(S)/γ-Al2O3 with X = Al, Ga, and In in diesel fuel dehydrosulfurization increases in the order Al < Ga < In. For catalysts in which the heteroatom is an element of the iron triad, the order of the increasing activities is Fe < Co < Ni. The highest activity in both reactions was observed for catalysts based on InMo6-HPC and NiMo6-HPC: the residual sulfur in the hydrogenizates obtained over them at 320°C was 2.5 times lower than over a conventional ammonium paramolybdate-based catalyst, whereas the degree of hydrogenation of polycyclic aromatic hydrocarbons (PAH) was 15–16 rel. % higher. More... »

PAGES

220-227

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0023158409020116

DOI

http://dx.doi.org/10.1134/s0023158409020116

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1030157664


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