Kinetics and mechanism of chemical reactions in the H2/O2/N2 flame at atmospheric pressure View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2009-03

AUTHORS

O. P. Korobeinichev, A. G. Shmakov, I. V. Rybitskaya, T. A. Bol’shova, A. A. Chernov, D. A. Knyaz’kov, A. A. Konnov

ABSTRACT

The kinetics and mechanism of chemical reactions in the H2/O2/N2 flame were studied experimentally and by simulating the structure of premixed laminar flat atmospheric H2/O2/N2 flames of different initial compositions. The concentration profiles for stable compounds (H2, O2, and H2O), H atoms, and OH• radicals in flames were measured by molecular-beam sampling mass spectrometry using soft electron-impact ionization. The experimental data thus obtained are in good agreement with the results of simulations in terms of three familiar kinetic mechanisms, suggesting that these mechanisms are applicable to the description of the flame structure in hydrogen-oxygen mixtures at atmospheric pressure. More... »

PAGES

156-161

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0023158409020025

DOI

http://dx.doi.org/10.1134/s0023158409020025

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1001689406


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "familyName": "Korobeinichev", 
        "givenName": "O. P.", 
        "id": "sg:person.012337071637.17", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012337071637.17"
        ], 
        "type": "Person"
      }, 
      {
        "familyName": "Shmakov", 
        "givenName": "A. G.", 
        "id": "sg:person.011304553263.64", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011304553263.64"
        ], 
        "type": "Person"
      }, 
      {
        "familyName": "Rybitskaya", 
        "givenName": "I. V.", 
        "id": "sg:person.07571142563.75", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07571142563.75"
        ], 
        "type": "Person"
      }, 
      {
        "familyName": "Bol\u2019shova", 
        "givenName": "T. A.", 
        "id": "sg:person.011003726033.66", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011003726033.66"
        ], 
        "type": "Person"
      }, 
      {
        "familyName": "Chernov", 
        "givenName": "A. A.", 
        "id": "sg:person.016352542246.97", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016352542246.97"
        ], 
        "type": "Person"
      }, 
      {
        "familyName": "Knyaz\u2019kov", 
        "givenName": "D. A.", 
        "id": "sg:person.012002027033.02", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012002027033.02"
        ], 
        "type": "Person"
      }, 
      {
        "familyName": "Konnov", 
        "givenName": "A. A.", 
        "id": "sg:person.013100741721.27", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013100741721.27"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1016/s0010-2180(99)00029-2", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1000961514"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1080/00102200490487175", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1006869656"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/kin.20026", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1008134710"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0010-2180(78)90056-1", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1012667031"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0010-2180(78)90056-1", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1012667031"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/kin.20036", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1013970703"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1098/rspa.1970.0113", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1018001539"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0082-0784(65)80150-3", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1020426307"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1080/00102208108946961", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1030727967"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0010-2180(99)00030-9", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1032242027"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1080/00102209308907668", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1033172287"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.combustflame.2005.03.017", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1035077589"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1080/00102209408935360", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1036466117"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0082-0784(65)80196-5", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1039824166"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.combustflame.2005.10.004", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1042427606"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.proci.2004.08.252", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1044219493"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.proci.2004.08.172", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1048362604"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0082-0784(06)80276-6", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1050177868"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1063/1.1699226", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1057769758"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1063/1.1723738", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1057790612"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1063/1.1748524", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1057810668"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2009-03", 
    "datePublishedReg": "2009-03-01", 
    "description": "The kinetics and mechanism of chemical reactions in the H2/O2/N2 flame were studied experimentally and by simulating the structure of premixed laminar flat atmospheric H2/O2/N2 flames of different initial compositions. The concentration profiles for stable compounds (H2, O2, and H2O), H atoms, and OH\u2022 radicals in flames were measured by molecular-beam sampling mass spectrometry using soft electron-impact ionization. The experimental data thus obtained are in good agreement with the results of simulations in terms of three familiar kinetic mechanisms, suggesting that these mechanisms are applicable to the description of the flame structure in hydrogen-oxygen mixtures at atmospheric pressure.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1134/s0023158409020025", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1136331", 
        "issn": [
          "0023-1584", 
          "0453-8811"
        ], 
        "name": "Kinetics and Catalysis", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "2", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "50"
      }
    ], 
    "name": "Kinetics and mechanism of chemical reactions in the H2/O2/N2 flame at atmospheric pressure", 
    "pagination": "156-161", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "080ba9e22a7c21b68b3f36ab70ae988f787ba51894853daf19d6b7a12546e7b8"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1134/s0023158409020025"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1001689406"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1134/s0023158409020025", 
      "https://app.dimensions.ai/details/publication/pub.1001689406"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-11T09:11", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000338_0000000338/records_47976_00000000.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1134/S0023158409020025"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s0023158409020025'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s0023158409020025'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s0023158409020025'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s0023158409020025'


 

This table displays all metadata directly associated to this object as RDF triples.

153 TRIPLES      21 PREDICATES      47 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1134/s0023158409020025 schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author Nd2e1f55a23cd4c0c8aaffaba735833c1
4 schema:citation https://doi.org/10.1002/kin.20026
5 https://doi.org/10.1002/kin.20036
6 https://doi.org/10.1016/0010-2180(78)90056-1
7 https://doi.org/10.1016/j.combustflame.2005.03.017
8 https://doi.org/10.1016/j.combustflame.2005.10.004
9 https://doi.org/10.1016/j.proci.2004.08.172
10 https://doi.org/10.1016/j.proci.2004.08.252
11 https://doi.org/10.1016/s0010-2180(99)00029-2
12 https://doi.org/10.1016/s0010-2180(99)00030-9
13 https://doi.org/10.1016/s0082-0784(06)80276-6
14 https://doi.org/10.1016/s0082-0784(65)80150-3
15 https://doi.org/10.1016/s0082-0784(65)80196-5
16 https://doi.org/10.1063/1.1699226
17 https://doi.org/10.1063/1.1723738
18 https://doi.org/10.1063/1.1748524
19 https://doi.org/10.1080/00102200490487175
20 https://doi.org/10.1080/00102208108946961
21 https://doi.org/10.1080/00102209308907668
22 https://doi.org/10.1080/00102209408935360
23 https://doi.org/10.1098/rspa.1970.0113
24 schema:datePublished 2009-03
25 schema:datePublishedReg 2009-03-01
26 schema:description The kinetics and mechanism of chemical reactions in the H2/O2/N2 flame were studied experimentally and by simulating the structure of premixed laminar flat atmospheric H2/O2/N2 flames of different initial compositions. The concentration profiles for stable compounds (H2, O2, and H2O), H atoms, and OH• radicals in flames were measured by molecular-beam sampling mass spectrometry using soft electron-impact ionization. The experimental data thus obtained are in good agreement with the results of simulations in terms of three familiar kinetic mechanisms, suggesting that these mechanisms are applicable to the description of the flame structure in hydrogen-oxygen mixtures at atmospheric pressure.
27 schema:genre research_article
28 schema:inLanguage en
29 schema:isAccessibleForFree false
30 schema:isPartOf N6766ad2f0afd4b4283f9083f5cce4367
31 Na8e262d432324fb4bb43eb4ae2f97664
32 sg:journal.1136331
33 schema:name Kinetics and mechanism of chemical reactions in the H2/O2/N2 flame at atmospheric pressure
34 schema:pagination 156-161
35 schema:productId N3bfd050734e940f58d960b55840875ac
36 N7feda773021f4613ac9242e6ee943593
37 Nac527453cd494b01a0c3ef683adb67ea
38 schema:sameAs https://app.dimensions.ai/details/publication/pub.1001689406
39 https://doi.org/10.1134/s0023158409020025
40 schema:sdDatePublished 2019-04-11T09:11
41 schema:sdLicense https://scigraph.springernature.com/explorer/license/
42 schema:sdPublisher Nb5fd1aa672f64661859c3e5f4df853ca
43 schema:url http://link.springer.com/10.1134/S0023158409020025
44 sgo:license sg:explorer/license/
45 sgo:sdDataset articles
46 rdf:type schema:ScholarlyArticle
47 N1f80e896e9c24639a45df7e84af518d3 rdf:first sg:person.011003726033.66
48 rdf:rest Ndb602285c66f4f9ca6b269c729da3aa9
49 N3bfd050734e940f58d960b55840875ac schema:name doi
50 schema:value 10.1134/s0023158409020025
51 rdf:type schema:PropertyValue
52 N4c5093c75a3a4c5897788ff16e3081ca rdf:first sg:person.012002027033.02
53 rdf:rest N5eddd094bb4b4cc6831391d2c9f6bb5a
54 N5eddd094bb4b4cc6831391d2c9f6bb5a rdf:first sg:person.013100741721.27
55 rdf:rest rdf:nil
56 N6766ad2f0afd4b4283f9083f5cce4367 schema:volumeNumber 50
57 rdf:type schema:PublicationVolume
58 N7d4bbe34e9bb4b6786eba8feaddde85f rdf:first sg:person.07571142563.75
59 rdf:rest N1f80e896e9c24639a45df7e84af518d3
60 N7feda773021f4613ac9242e6ee943593 schema:name dimensions_id
61 schema:value pub.1001689406
62 rdf:type schema:PropertyValue
63 Na8e262d432324fb4bb43eb4ae2f97664 schema:issueNumber 2
64 rdf:type schema:PublicationIssue
65 Nac527453cd494b01a0c3ef683adb67ea schema:name readcube_id
66 schema:value 080ba9e22a7c21b68b3f36ab70ae988f787ba51894853daf19d6b7a12546e7b8
67 rdf:type schema:PropertyValue
68 Nb5fd1aa672f64661859c3e5f4df853ca schema:name Springer Nature - SN SciGraph project
69 rdf:type schema:Organization
70 Ncea7562c13b648dd817142729dc88700 rdf:first sg:person.011304553263.64
71 rdf:rest N7d4bbe34e9bb4b6786eba8feaddde85f
72 Nd2e1f55a23cd4c0c8aaffaba735833c1 rdf:first sg:person.012337071637.17
73 rdf:rest Ncea7562c13b648dd817142729dc88700
74 Ndb602285c66f4f9ca6b269c729da3aa9 rdf:first sg:person.016352542246.97
75 rdf:rest N4c5093c75a3a4c5897788ff16e3081ca
76 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
77 schema:name Chemical Sciences
78 rdf:type schema:DefinedTerm
79 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
80 schema:name Physical Chemistry (incl. Structural)
81 rdf:type schema:DefinedTerm
82 sg:journal.1136331 schema:issn 0023-1584
83 0453-8811
84 schema:name Kinetics and Catalysis
85 rdf:type schema:Periodical
86 sg:person.011003726033.66 schema:familyName Bol’shova
87 schema:givenName T. A.
88 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011003726033.66
89 rdf:type schema:Person
90 sg:person.011304553263.64 schema:familyName Shmakov
91 schema:givenName A. G.
92 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011304553263.64
93 rdf:type schema:Person
94 sg:person.012002027033.02 schema:familyName Knyaz’kov
95 schema:givenName D. A.
96 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012002027033.02
97 rdf:type schema:Person
98 sg:person.012337071637.17 schema:familyName Korobeinichev
99 schema:givenName O. P.
100 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012337071637.17
101 rdf:type schema:Person
102 sg:person.013100741721.27 schema:familyName Konnov
103 schema:givenName A. A.
104 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013100741721.27
105 rdf:type schema:Person
106 sg:person.016352542246.97 schema:familyName Chernov
107 schema:givenName A. A.
108 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016352542246.97
109 rdf:type schema:Person
110 sg:person.07571142563.75 schema:familyName Rybitskaya
111 schema:givenName I. V.
112 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07571142563.75
113 rdf:type schema:Person
114 https://doi.org/10.1002/kin.20026 schema:sameAs https://app.dimensions.ai/details/publication/pub.1008134710
115 rdf:type schema:CreativeWork
116 https://doi.org/10.1002/kin.20036 schema:sameAs https://app.dimensions.ai/details/publication/pub.1013970703
117 rdf:type schema:CreativeWork
118 https://doi.org/10.1016/0010-2180(78)90056-1 schema:sameAs https://app.dimensions.ai/details/publication/pub.1012667031
119 rdf:type schema:CreativeWork
120 https://doi.org/10.1016/j.combustflame.2005.03.017 schema:sameAs https://app.dimensions.ai/details/publication/pub.1035077589
121 rdf:type schema:CreativeWork
122 https://doi.org/10.1016/j.combustflame.2005.10.004 schema:sameAs https://app.dimensions.ai/details/publication/pub.1042427606
123 rdf:type schema:CreativeWork
124 https://doi.org/10.1016/j.proci.2004.08.172 schema:sameAs https://app.dimensions.ai/details/publication/pub.1048362604
125 rdf:type schema:CreativeWork
126 https://doi.org/10.1016/j.proci.2004.08.252 schema:sameAs https://app.dimensions.ai/details/publication/pub.1044219493
127 rdf:type schema:CreativeWork
128 https://doi.org/10.1016/s0010-2180(99)00029-2 schema:sameAs https://app.dimensions.ai/details/publication/pub.1000961514
129 rdf:type schema:CreativeWork
130 https://doi.org/10.1016/s0010-2180(99)00030-9 schema:sameAs https://app.dimensions.ai/details/publication/pub.1032242027
131 rdf:type schema:CreativeWork
132 https://doi.org/10.1016/s0082-0784(06)80276-6 schema:sameAs https://app.dimensions.ai/details/publication/pub.1050177868
133 rdf:type schema:CreativeWork
134 https://doi.org/10.1016/s0082-0784(65)80150-3 schema:sameAs https://app.dimensions.ai/details/publication/pub.1020426307
135 rdf:type schema:CreativeWork
136 https://doi.org/10.1016/s0082-0784(65)80196-5 schema:sameAs https://app.dimensions.ai/details/publication/pub.1039824166
137 rdf:type schema:CreativeWork
138 https://doi.org/10.1063/1.1699226 schema:sameAs https://app.dimensions.ai/details/publication/pub.1057769758
139 rdf:type schema:CreativeWork
140 https://doi.org/10.1063/1.1723738 schema:sameAs https://app.dimensions.ai/details/publication/pub.1057790612
141 rdf:type schema:CreativeWork
142 https://doi.org/10.1063/1.1748524 schema:sameAs https://app.dimensions.ai/details/publication/pub.1057810668
143 rdf:type schema:CreativeWork
144 https://doi.org/10.1080/00102200490487175 schema:sameAs https://app.dimensions.ai/details/publication/pub.1006869656
145 rdf:type schema:CreativeWork
146 https://doi.org/10.1080/00102208108946961 schema:sameAs https://app.dimensions.ai/details/publication/pub.1030727967
147 rdf:type schema:CreativeWork
148 https://doi.org/10.1080/00102209308907668 schema:sameAs https://app.dimensions.ai/details/publication/pub.1033172287
149 rdf:type schema:CreativeWork
150 https://doi.org/10.1080/00102209408935360 schema:sameAs https://app.dimensions.ai/details/publication/pub.1036466117
151 rdf:type schema:CreativeWork
152 https://doi.org/10.1098/rspa.1970.0113 schema:sameAs https://app.dimensions.ai/details/publication/pub.1018001539
153 rdf:type schema:CreativeWork
 




Preview window. Press ESC to close (or click here)


...