Kinetics and mechanism of chemical reactions in the H2/O2/N2 flame at atmospheric pressure View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2009-03

AUTHORS

O. P. Korobeinichev, A. G. Shmakov, I. V. Rybitskaya, T. A. Bol’shova, A. A. Chernov, D. A. Knyaz’kov, A. A. Konnov

ABSTRACT

The kinetics and mechanism of chemical reactions in the H2/O2/N2 flame were studied experimentally and by simulating the structure of premixed laminar flat atmospheric H2/O2/N2 flames of different initial compositions. The concentration profiles for stable compounds (H2, O2, and H2O), H atoms, and OH• radicals in flames were measured by molecular-beam sampling mass spectrometry using soft electron-impact ionization. The experimental data thus obtained are in good agreement with the results of simulations in terms of three familiar kinetic mechanisms, suggesting that these mechanisms are applicable to the description of the flame structure in hydrogen-oxygen mixtures at atmospheric pressure. More... »

PAGES

156-161

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0023158409020025

DOI

http://dx.doi.org/10.1134/s0023158409020025

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1001689406


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