Structure Of 1,4-Dihydro-1,4-Diazocine With Three Annulated Pyrazole Rings View Full Text


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Article Info

DATE

2021-03

AUTHORS

G. V. Romanenko, S. E. Tolstikov, V. I. Ovcharenko

ABSTRACT

The structures of four products formed in the interaction of lithiated N-methylpyrazole with isoamyl nitrite are determined. One of the reaction products is found to be a 1,4-diazocine derivative–a medium-sized condensed heterocycle in which three pyrazole moieties are annulated to an eight-membered heterocycle and yet another pyrazole moiety is located in a side chain. This molecular structure of the compound blocks the transformation of the eight-membered heterocycle into the bicyclic derivative through a transannular reaction. More... »

PAGES

431-435

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0022476621030094

DOI

http://dx.doi.org/10.1134/s0022476621030094

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1137264190


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