Structure Of Lanthanide Semiquinolates With Nitrogen-Containing Ligands View Full Text


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Article Info

DATE

2020-10-13

AUTHORS

G. V. Romanenko, S. V. Fokin, G. A. Letyagin, A. S. Bogomyakov, V. I. Ovcharenko

ABSTRACT

Molecular and crystal structures are determined for a series of mixed-ligand mononuclear compounds of lanthanides (Ln) with the 3,6-di(tert-butyl)-1,2-benzoquinone (SQ) anion radical and bidentate nitrogen-containing ligands (L) of the composition [Ln(SQ)3(L)], where Ln is Tb or Dy, L is 2,2′-bipyridine (bipy); Ln is Eu, L is 1,10-phenanthroline (phen) or N,N,N′,N′-tetramethylethylenediamine (tmen). It is confirmed that the introduction of bidentate L significantly increases the stability of lanthanide semiquinolates in both liquid and solid phases. More... »

PAGES

1594-1598

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s002247662010011x

DOI

http://dx.doi.org/10.1134/s002247662010011x

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1133502713


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