1,3-Di(4-Pyridyl)Triazene: A New Ligand for the Synthesis of Coordination Polymers View Full Text


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Article Info

DATE

2020-05

AUTHORS

G. V. Romanenko, S. E. Tolstikov, E. Yu. Fursova, V. I. Ovcharenko

ABSTRACT

4,4′-(Triaz-1-ene-1,3-diyl)dipyridine (L) and the first transition metal complex with it are synthesized. It is found that the solid phase of isolated solvate [Cu(hfac)2L]·0.5MePh, where hfac is hexafluoroacetylacetonate, consists of polymer chains inside which L acts as a bridge, linking together Cu(hfac)2 moieties by N atoms of pyridine rings. The chains, in turn, are arranged into layers by H bonds. The result shows that L can be a bridging ligand in the synthesis of new coordination polymers. More... »

PAGES

707-711

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0022476620050054

DOI

http://dx.doi.org/10.1134/s0022476620050054

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1129988788


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